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Hydrothermal synthesis and thermoelectric properties of PbS

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19 nov 2016

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XRD pattern of hydrothermally synthesized PbS powder.
XRD pattern of hydrothermally synthesized PbS powder.
SEM image of hydrothermally synthesized PbS powder.
SEM image of hydrothermally synthesized PbS powder.
XRD patterns of high pressure sintered bulk PbS doped with Bi.
XRD patterns of high pressure sintered bulk PbS doped with Bi.
SEM image of high pressure sintered bulk sample PbS.
SEM image of high pressure sintered bulk sample PbS.
Temperature dependence of Seebeck coefficient for PbS and Bi0.01Pb0.99S.
Temperature dependence of Seebeck coefficient for PbS and Bi0.01Pb0.99S.
Temperature dependence of electrical resistivity for PbS and Bi0.01Pb0.99S.
Temperature dependence of electrical resistivity for PbS and Bi0.01Pb0.99S.
Temperature dependence of power factor for PbS and Bi0.01Pb0.99S.
Temperature dependence of power factor for PbS and Bi0.01Pb0.99S.
Temperature dependence of thermal conductivity for PbS and Bi0.01Pb0.99S.
Temperature dependence of thermal conductivity for PbS and Bi0.01Pb0.99S.
Temperature dependence of ZT of PbS and Bi0.01Pb0.99S.
Temperature dependence of ZT of PbS and Bi0.01Pb0.99S.

The values of ρ, a and γ obtained from the formula ρ = ρ0+aTγ_

Sampleρ [10 −6Ω·cm]a(10−16)γ
PbS67.552.6810.82
Bi0.01Pb0.99S11.434.826.12

Electrical transport properties of PbS and Bi doped PbS samples (BixPb1−xS) at room temperature_

SampleCarrier concentration [1018 cm−3]Hall mobility [cm2/V·s]Hall coefficient RH [cm−3]Resistivity [10−3 Ω·cm]Seebeck coefficient S [μV/K]
PbS7.3694.120.859.02220.44
Bi0.005Pb0.995S26.313.313−0.2471.61−134.29
Bi0.01Pb0.99S45.215133.99−0.141.03−112.27
Bi0.0l5Pb0.985S45.387126.83−0.141.08−48.48