<abstract xmlns="http://www.w3.org/1999/xhtml"> A study has been conducted on the effects of partial, 10 % Co substitution by Fe in the perovskite Sr0.775Y0.225CoO3-δ compound. The XRD data show that the resulted samples of Fe-free and Fe-doped compounds exhibit good 314 single phase quality with a tetragonal I4/mmm crystal structure. The measured M-T curves display the typical feature of ferromagnetic (FM) transition at 335 K for the Fe-free sample, while showing significantly degraded FM ordering for the 10 % Fe-doped sample. The oxygen deficiency determined fro|m our 10 % Fe doped sample is found to decrease by only 0.025. Further detailed analysis of the XRD data also reveals distinctly different structural changes in the Co-O slabs compared to the 50 % Fe-doped sample which exhibits a complete suppression of FM order. The results of this study, thus, have revealed the close relations among the changes induced by Fe doping in the magnetic ordering of crystal, and its oxygen content as well as the associated local structure in the Co-O layers responsible for the magnetic properties in the compound. </abstract>

A study has been conducted on the effects of partial, 10 % Co substitution by Fe in the perovskite Sr0.775Y0.225CoO3-δ compound. The XRD data show that the resulted samples of Fe-free and Fe-doped compounds exhibit good 314 single phase quality with a tetragonal I4/mmm crystal structure. The measured M-T curves display the typical feature of ferromagnetic (FM) transition at 335 K for the Fe-free sample, while showing significantly degraded FM ordering for the 10 % Fe-doped sample. The oxygen deficiency determined fro|m our 10 % Fe doped sample is found to decrease by only 0.025. Further detailed analysis of the XRD data also reveals distinctly different structural changes in the Co-O slabs compared to the 50 % Fe-doped sample which exhibits a complete suppression of FM order. The results of this study, thus, have revealed the close relations among the changes induced by Fe doping in the magnetic ordering of crystal, and its oxygen content as well as the associated local structure in the Co-O layers responsible for the magnetic properties in the compound.

Effects of partial Co replacement by Fe in Sr0.775Y0.225CoO3-δ on its magnetic property, oxygen deficiency and crystal structure

Physics of Photonics and Magnetism, Dept. of Physics, Faculty of Mathematics and Natural Science, Institute Technology Bandung, Jl. Ganesha 10, Bandung 40132, Indonesia

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Effects of partial Co replacement by Fe in SrYCoO on its magnetic property, oxygen deficiency and crystal structure

A study has been conducted on the effects of partial, 10 % Co substitution by Fe in the perovskite Sr0.775Y0.225CoO3-δ compound. The XRD data show that the...

Effects of partial Co replacement by Fe in Sr_0.775Y_0.225CoO_3-δ on its magnetic property, oxygen deficiency and crystal structure

Publicado en línea: 30 ago 2016

Páginas: 579 - 587

Recibido: 25 nov 2014

Aceptado: 05 may 2015

DOI: https://doi.org/10.1515/msp-2015-0078

Palabras clave
perovskite Sr0.775Y0.225CoO3-δ compound, ferromagnetic compound, oxygen content

© 2016

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Effects of partial Co replacement by Fe in Sr0.775Y0.225CoO3-δ on its magnetic property, oxygen deficiency and crystal structure

Publicado en línea: 30 ago 2016

Páginas: 579 - 587

Recibido: 25 nov 2014

Aceptado: 05 may 2015

DOI: https://doi.org/10.1515/msp-2015-0078

Palabras claveperovskite Sr0.775Y0.225CoO3-δ compound, ferromagnetic compound, oxygen content

© 2016

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Effects of partial Co replacement by Fe in Sr_0.775Y_0.225CoO_3-δ on its magnetic property, oxygen deficiency and crystal structure

Palabras clave
perovskite Sr0.775Y0.225CoO3-δ compound, ferromagnetic compound, oxygen content