<abstract xmlns="http://www.w3.org/1999/xhtml"> We report here the structure of new spiro-derivative, namely methyl (2R,4R)-4-(5-methylthiazol- 2-ylamino)spiro[chroman-2,2’-chromene]-3’-carboxylate, C23H20N2O4S, which crystallizes as racemate in the space group P-1. In this compound, the chromanone moiety consists of a benzene ring fused with a sixmembered heterocyclic ring which adopts a distorted half-chair conformation. The molecules are linked by a combination of N–H⋯N hydrogen bonds and weak C–H⋯O, C-H⋯S, C-H⋯π, inter- and intramolecular interactions resulting in a two-dimensional network in the crystal structure.</abstract>

We report here the structure of new spiro-derivative, namely methyl (2R,4R)-4-(5-methylthiazol- 2-ylamino)spiro[chroman-2,2’-chromene]-3’-carboxylate, C23H20N2O4S, which crystallizes as racemate in the space group P-1. In this compound, the chromanone moiety consists of a benzene ring fused with a sixmembered heterocyclic ring which adopts a distorted half-chair conformation. The molecules are linked by a combination of N–H⋯N hydrogen bonds and weak C–H⋯O, C-H⋯S, C-H⋯π, inter- and intramolecular interactions resulting in a two-dimensional network in the crystal structure.

Crystal and electronic structure, N–H⋯N and C–H⋯O interactions in novel spiro-[chroman-chromene]-carboxylate

Acta Chimica Slovaca

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

We report here the structure of new spiro-derivative, namely methyl (2R,4R)-4-(5-methylthiazol- 2-ylamino)spiro[chroman-2,2’-chromene]-3’-carboxylate,...

Crystal and electronic structure, N–H⋯N and C–H⋯O interactions in novel spiro-[chroman-chromene]-carboxylate

Publicado en línea: 23 jun 2017

Páginas: 74 - 78

DOI: https://doi.org/10.1515/acs-2017-0013

Palabras clave
carboxylates, crystal structure, spiro chroman-chromene, hydrogen bonding

© Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Crystal and electronic structure, N–H⋯N and C–H⋯O interactions in novel spiro-[chroman-chromene]-carboxylate

Publicado en línea: 23 jun 2017

Páginas: 74 - 78

DOI: https://doi.org/10.1515/acs-2017-0013

Palabras clavecarboxylates, crystal structure, spiro chroman-chromene, hydrogen bonding

© Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Palabras clave
carboxylates, crystal structure, spiro chroman-chromene, hydrogen bonding