<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml">A method was developed to attach 2,2-bipyridine (BP) onto a silica gel surface by a two-step reaction. The first step consisted of a reaction between the matrix and a silylating agent, 3-chloropropyltrimethoxysilane. In the second step of the reaction, a ligand molecule was attached onto Si-CPTS, yielding the product Si-BP. The modified material contained 0.431±0.01 mmol of 2,2-bipyridine per gram of modified silica, as confirmed by FT-IR spectra of the proposed structure. The surface modification was characterized by the BET technique, which revealed a decrease in the surface area from 614 to 450 m2 g-1. The series of adsorption isotherms for the metal ions were adjusted to fit a modified Langmuir equation. The maximum number of moles of copper, cadmium and lead ions adsorbed was 0.64, 0.53, and 0.54 mmol g-1, respectively. The surface saturation was calculated as φ fraction and the values obtained, Cu(II) = 1.160, Cd(II) = 1.044 and Pb(II) = 0.997, suggest a type 1:1 metal-ligand complex.</abstract>

A method was developed to attach 2,2-bipyridine (BP) onto a silica gel surface by a two-step reaction. The first step consisted of a reaction between the matrix and a silylating agent, 3-chloropropyltrimethoxysilane. In the second step of the reaction, a ligand molecule was attached onto Si-CPTS, yielding the product Si-BP. The modified material contained 0.431±0.01 mmol of 2,2-bipyridine per gram of modified silica, as confirmed by FT-IR spectra of the proposed structure. The surface modification was characterized by the BET technique, which revealed a decrease in the surface area from 614 to 450 m2 g-1. The series of adsorption isotherms for the metal ions were adjusted to fit a modified Langmuir equation. The maximum number of moles of copper, cadmium and lead ions adsorbed was 0.64, 0.53, and 0.54 mmol g-1, respectively. The surface saturation was calculated as φ fraction and the values obtained, Cu(II) = 1.160, Cd(II) = 1.044 and Pb(II) = 0.997, suggest a type 1:1 metal-ligand complex.

Attachment of 2,2-bipyridine onto a silica gel for application as a sequestering agent for copper, cadmium and lead ions from an aqueous medium

Departamento de Física e Química, FEIS/UNESP-Univ. Estadual Paulista, C.P. 31, 15385-000, Ilha Solteira, SP, Brazil

Departamento de Química e Bioquímica, IB-UNESP-Univ. Estadual Paulista, C.P.510, 18618-000 Botucatu, SP, Brazil

Departamento de Química, UFMS, C.P. 549, 79074-460, Campo Grande, MS, Brazil

INCT de Bioanalítica - UNICAMP, C.P. 6154, 13084-971 Campinas, SP, Brazil

Polish Journal of Chemical Technology

A method was developed to attach 2,2-bipyridine (BP) onto a silica gel surface by a two-step reaction. The first step consisted of a reaction between the...

Attachment of 2,2-bipyridine onto a silica gel for application as a sequestering agent for copper, cadmium and lead ions from an aqueous medium

Online veröffentlicht: 02. Jan. 2012

Seitenbereich: 28 - 33

DOI: https://doi.org/10.2478/v10026-011-0045-2

Schlüsselwörter
2, 2-Bipyridine, silica gel, adsorption, metal ions

This content is open access.

Attachment of 2,2-bipyridine onto a silica gel for application as a sequestering agent for copper, cadmium and lead ions from an aqueous medium

Online veröffentlicht: 02. Jan. 2012

Seitenbereich: 28 - 33

DOI: https://doi.org/10.2478/v10026-011-0045-2

Schlüsselwörter2, 2-Bipyridine, silica gel, adsorption, metal ions

This content is open access.

Schlüsselwörter
2, 2-Bipyridine, silica gel, adsorption, metal ions