<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml"><p>Attempts were made to isolate 1,2-epoxybutane-3-ol and 2,3-epoxybutane-1-ol from post-reaction mixtures left after the epoxidation of 1-butene-3-ol and 2-butene-1-ol with hydrogen peroxide by thin film distillation. From the raw mixture containing about 8.3 wt% of the epoxide at the first stage the concentration of epoxide is increased to 32 wt%. At the second stage of distillation the epoxide fraction is concentrated to about 76 wt%. After the third stage of thin film distillation the epoxide fraction of 99.6% purity can be obtained. The concentration of this fraction by azeotropic distillation with n-propanol as an azeotropic agent permits obtaining epoxide of 99.6 wt% purity.</p></abstract>

Attempts were made to isolate 1,2-epoxybutane-3-ol and 2,3-epoxybutane-1-ol from post-reaction mixtures left after the epoxidation of 1-butene-3-ol and 2-butene-1-ol with hydrogen peroxide by thin film distillation. From the raw mixture containing about 8.3 wt% of the epoxide at the first stage the concentration of epoxide is increased to 32 wt%. At the second stage of distillation the epoxide fraction is concentrated to about 76 wt%. After the third stage of thin film distillation the epoxide fraction of 99.6% purity can be obtained. The concentration of this fraction by azeotropic distillation with n-propanol as an azeotropic agent permits obtaining epoxide of 99.6 wt% purity.

Isolation of 1,2-epoxybutane-3-ol and 2,3-epoxybutane-1-ol from post-reaction mixtures

Institute of Organic Chemical Technology, West Pomeranian University of Technology Szczecin, ul. Pułaskiego 10, 70-322 Szczecin, Poland

Polish Journal of Chemical Technology

Attempts were made to isolate 1,2-epoxybutane-3-ol and 2,3-epoxybutane-1-ol from post-reaction mixtures left after the epoxidation of 1-butene-3-ol and...

Isolation of 1,2-epoxybutane-3-ol and 2,3-epoxybutane-1-ol from post-reaction mixtures

Online veröffentlicht: 09. Juli 2010

Seitenbereich: 29 - 32

DOI: https://doi.org/10.2478/v10026-010-0014-1

Schlüsselwörter
thin film distillation, isolation of epoxides

This content is open access.

Isolation of 1,2-epoxybutane-3-ol and 2,3-epoxybutane-1-ol from post-reaction mixtures

Online veröffentlicht: 09. Juli 2010

Seitenbereich: 29 - 32

DOI: https://doi.org/10.2478/v10026-010-0014-1

Schlüsselwörterthin film distillation, isolation of epoxides

This content is open access.

Schlüsselwörter
thin film distillation, isolation of epoxides