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ToF-SIMS studies of the surface of Pd/ZrO2-TiO2 catalyst used in the hydrodechlorination process


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Time-of-flight secondary ion mass spectrometry (ToF-SIMS) was used in order to obtain the information about the surface composition of Pd/ZrO2-TiO2 catalyst and to estimate the changes in the concentration of particular components on its surface during the hydrodechlorination of CCl4. The results demonstrated that the hydrodechlorination process led to the increase in the concentration of chlorine and the drop in the amount of surface accessible palladium, while the quantity of Pd-Cl bounds did not change considerably. It suggested that the presence of ZrO2 protected the surface of the studied catalyst against the formation of PdCl2.

eISSN:
1899-4741
ISSN:
1509-8117
Sprache:
Englisch
Zeitrahmen der Veröffentlichung:
4 Hefte pro Jahr
Fachgebiete der Zeitschrift:
Industrielle Chemie, Biotechnologie, Chemieingenieurwesen, Verfahrenstechnik