<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml">The results of the epoxidation of 2-buten-1-ol with 30 wt% hydrogen peroxide have been presented. As a solvent methanol was used. The process was carried out over the titanium silicalite catalysts: Ti-MCM-41 and Ti-MCM-48. The influence of temperature (20 - 120°C), the molar ratio of CRA/H2O2 (5:1 - 5:1), methanol concentration (5 - 90 wt%), catalyst concentration (0.1 - 5.0 wt%) and the reaction time (30 - 300 min) was investigated. The obtained results were used for the determination of optimum conditions of running the epoxidation process of 2-buten-1-ol.</abstract>

The results of the epoxidation of 2-buten-1-ol with 30 wt% hydrogen peroxide have been presented. As a solvent methanol was used. The process was carried out over the titanium silicalite catalysts: Ti-MCM-41 and Ti-MCM-48. The influence of temperature (20 - 120°C), the molar ratio of CRA/H2O2 (5:1 - 5:1), methanol concentration (5 - 90 wt%), catalyst concentration (0.1 - 5.0 wt%) and the reaction time (30 - 300 min) was investigated. The obtained results were used for the determination of optimum conditions of running the epoxidation process of 2-buten-1-ol.

Epoxidation of 2-buten-1-ol over Ti-MCM-41 and Ti-MCM-48 titanium silicalite catalysts

Faculty of Technology and Chemical Engineering, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, Poland

Polish Journal of Chemical Technology

The results of the epoxidation of 2-buten-1-ol with 30 wt% hydrogen peroxide have been presented. As a solvent methanol was used. The process was carried out...

Epoxidation of 2-buten-1-ol over Ti-MCM-41 and Ti-MCM-48 titanium silicalite catalysts

Online veröffentlicht: 06. Nov. 2007

Seitenbereich: 1 - 4

DOI: https://doi.org/10.2478/v10026-007-0041-8

Schlüsselwörter
epoxidation, 2,3-epoxybutan-1-ol, Ti-MCM-41, Ti-MCM-48

This content is open access.

Epoxidation of 2-buten-1-ol over Ti-MCM-41 and Ti-MCM-48 titanium silicalite catalysts

Online veröffentlicht: 06. Nov. 2007

Seitenbereich: 1 - 4

DOI: https://doi.org/10.2478/v10026-007-0041-8

Schlüsselwörterepoxidation, 2,3-epoxybutan-1-ol, Ti-MCM-41, Ti-MCM-48

This content is open access.

Schlüsselwörter
epoxidation, 2,3-epoxybutan-1-ol, Ti-MCM-41, Ti-MCM-48