Metamorphic tourmaline and its petrogenetic significance from the Maramureș Mountains (East Carpathians, Romania)

This study describes mineralogical and crystallochemical characteristics of metamorphic tourmalines from an Alpine shear zone in a Variscan metamorphic rock sequence from the Maramures region in the northern part of the East Carpathians. We use this mineral to unravel aspects of the evolution of the tourmaline bearing host rocks and compare the crystallo-chemical characteristics to other tourmalines from Alps. Petrographic and microstructural observations, as well as electron microprobe analyses on several zoned tourmalines and associated minerals (mica, feldspar) from mylonitic schist of the Rebra terrane (Maramureș Mountains), indicate that the pre-kinematic tourmalines belong to the alkali group (Na dominant), hydroxyl dominated on the crystallographic W-site and can be assigned to the species dravite and schorl. The tourmaline-bearing rocks have a metasedimentary protolith. The analysed porphyroblasts, rotated by simple shear, show corroded rim that are interpreted to have formed due to pressure release. Three main compositional zones were evidenced on a tourmaline porphyroblast: a core zone and two asymmetrically arranged inclusion-poor/free rims, all formed in pre-alpine prograde metamorphic conditions. Based on mineral microstructural relations and geothermobarometry (tourmaline–muscovite, tourmaline–plagioclase geothermometry and phengite geobarometry), the metamorphic peak conditions of the investigated Rebra terrane were evaluated to have been at a temperature of ca. 590 to 620 ± 22 °C and P_min = 5.5 - 6.0 ± 0.5 kbar. By observing dynamically recrystallized microstructures in quartz and feldspar in the shear zone a temperature of 350 - 400 °C was estimated and the quartz paleopiezometry outlined a differential stress of about 1.5 kbar that implied only minor chemical change in tourmaline outer zone.