<abstract xmlns="http://www.w3.org/1999/xhtml">The efficient reuse of homogeneous catalyst is important. Cation complex of [Ru(η6-p-cymene)(PPh3)(CH3CN) Cl]PF6 with different ligands was synthesized and characterized by infrared spectroscopy (IR), 1H-, 13C- and 31P-nuclear magnetic resonance spectroscopy (1H-, 13C- and 31P-NMR), element analysis (EA), and high resolution mass spectrometry (HR-MS). The complex was used as a catalyst for the hydrogen transfer reduction of carbonyl for the first time, presenting an excellent catalytic performance of 89%–98% conversion of acetophenone and its derivatives. The catalyst may be efficiently reused by the electro-adsorption of 10 times to one catalyst recovery. The cation [Ru] complex presented advantages of both homogeneous and heterogeneous catalysts.</abstract>

The efficient reuse of homogeneous catalyst is important. Cation complex of [Ru(η6-p-cymene)(PPh3)(CH3CN) Cl]PF6 with different ligands was synthesized and characterized by infrared spectroscopy (IR), 1H-, 13C- and 31P-nuclear magnetic resonance spectroscopy (1H-, 13C- and 31P-NMR), element analysis (EA), and high resolution mass spectrometry (HR-MS). The complex was used as a catalyst for the hydrogen transfer reduction of carbonyl for the first time, presenting an excellent catalytic performance of 89%–98% conversion of acetophenone and its derivatives. The catalyst may be efficiently reused by the electro-adsorption of 10 times to one catalyst recovery. The cation [Ru] complex presented advantages of both homogeneous and heterogeneous catalysts.

Ionic [Ru] complex with recyclability by electro-adsorption for efficient catalytic transfer hydrogenation of aryl ketones

School of Mathematics and Chemical Engineering, Changzhou Institute of Technology, Department of Chemical Engineering

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

The efficient reuse of homogeneous catalyst is important. Cation complex of [Ru(η6-p-cymene)(PPh3)(CH3CN) Cl]PF6 with different ligands was synthesized and...

Ionic [Ru] complex with recyclability by electro-adsorption for efficient catalytic transfer hydrogenation of aryl ketones

Online veröffentlicht: 29. Dez. 2017

Seitenbereich: 75 - 79

DOI: https://doi.org/10.1515/pjct-2017-0070

Schlüsselwörter
ionic Ru complex, transfer hydrogenation, electron-adsorption, catalyst recovery

© 2017 Chuan-Jun Yue et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Ionic [Ru] complex with recyclability by electro-adsorption for efficient catalytic transfer hydrogenation of aryl ketones

Online veröffentlicht: 29. Dez. 2017

Seitenbereich: 75 - 79

DOI: https://doi.org/10.1515/pjct-2017-0070

Schlüsselwörterionic Ru complex, transfer hydrogenation, electron-adsorption, catalyst recovery

© 2017 Chuan-Jun Yue et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Schlüsselwörter
ionic Ru complex, transfer hydrogenation, electron-adsorption, catalyst recovery