<abstract xmlns="http://www.w3.org/1999/xhtml">In this study, some types of composites consisting of multi-walled carbon nanotubes (MWCNTs) and spinel oxide (Co, Ni)3O4 were synthesized by simple evaporation method. These composites were characterized by UV–Vis diffuse reflectance spectroscopy, X-rays diffraction(XRD), Scanning electron microscopy (SEM) and specific surface area(SBET). The photocatalytic activity of the prepared composites was investigated by the following removal of Bismarck brown G (BBG) dye from its aqueous solutions. The obtained results showed that using MWCNTs in combination with spinel oxide to produced composites (spinel/MWCNTs) which succeeded in increasing the activity of spinel oxide and exhibited higher photocatalytic activity than spinel oxide alone. Also it was found that, multiwalled carbon nanotubes were successful in increasing the adsorption and improving the activity of photocatalytic degradation of Bismarck brown G dye(BBG). The obtained results showed that spinel/MWCNTs was more active in dye removal in comparison with each of spinel oxide and MWCNTs alone under the same reaction conditions. Also band gap energies for the prepared composites showed lower values in comparison with neat spinel. This point represents a promising observation as these composites can be excited using a lower energy radiation sources.</abstract>

In this study, some types of composites consisting of multi-walled carbon nanotubes (MWCNTs) and spinel oxide (Co, Ni)3O4 were synthesized by simple evaporation method. These composites were characterized by UV–Vis diffuse reflectance spectroscopy, X-rays diffraction(XRD), Scanning electron microscopy (SEM) and specific surface area(SBET). The photocatalytic activity of the prepared composites was investigated by the following removal of Bismarck brown G (BBG) dye from its aqueous solutions. The obtained results showed that using MWCNTs in combination with spinel oxide to produced composites (spinel/MWCNTs) which succeeded in increasing the activity of spinel oxide and exhibited higher photocatalytic activity than spinel oxide alone. Also it was found that, multiwalled carbon nanotubes were successful in increasing the adsorption and improving the activity of photocatalytic degradation of Bismarck brown G dye(BBG). The obtained results showed that spinel/MWCNTs was more active in dye removal in comparison with each of spinel oxide and MWCNTs alone under the same reaction conditions. Also band gap energies for the prepared composites showed lower values in comparison with neat spinel. This point represents a promising observation as these composites can be excited using a lower energy radiation sources.

Enhancement photocatalytic activity of spinel oxide (Co, Ni)3O4 by combination with carbon nanotubes

College of Science-Department of Chemistry

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Enhancement photocatalytic activity of spinel oxide (Co, Ni)O by combination with carbon nanotubes

In this study, some types of composites consisting of multi-walled carbon nanotubes (MWCNTs) and spinel oxide (Co, Ni)3O4 were synthesized by simple...

Enhancement photocatalytic activity of spinel oxide (Co, Ni)₃O₄ by combination with carbon nanotubes

Online veröffentlicht: 10. Okt. 2017

Seitenbereich: 61 - 67

DOI: https://doi.org/10.1515/pjct-2017-0050

Schlüsselwörter
MWCNT, spinel oxide, spinel/CNTs composite, Bismarck brown G degradation, photocatalytic activity

© 2017 Bashaer J. Kahdum et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Enhancement photocatalytic activity of spinel oxide (Co, Ni)3O4 by combination with carbon nanotubes

Online veröffentlicht: 10. Okt. 2017

Seitenbereich: 61 - 67

DOI: https://doi.org/10.1515/pjct-2017-0050

SchlüsselwörterMWCNT, spinel oxide, spinel/CNTs composite, Bismarck brown G degradation, photocatalytic activity

© 2017 Bashaer J. Kahdum et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Enhancement photocatalytic activity of spinel oxide (Co, Ni)₃O₄ by combination with carbon nanotubes

Schlüsselwörter
MWCNT, spinel oxide, spinel/CNTs composite, Bismarck brown G degradation, photocatalytic activity