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Effect of lead salts on phase, morphologies and photoluminescence of nanocrystalline PbMoO4 and PbWO4 synthesized by microwave radiation


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PbMoO4 and PbWO4 were successfully synthesized by microwave radiation using different lead salts (acetate, chloride, nitrate and sulfate) and Na2MO4 (M = Mo, W) in propylene glycol. The products were characterized by X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM, TEM), Fourier transform infrared (FT-IR), Raman spectroscopy and photoluminescence (PL) spectroscopy. In this research, morphologies, crystallization and photoluminescence of the products were influenced by the kinetics of anions, including the detection of M–O (M = Mo, W) stretching modes in the (MO4)2− tetrahedrons. Photoluminescence of PbMoO4 synthesized from Pb(NO3)2 and of PbWO4 synthesized from PbCl2 showed the strongest blue emission due to the electronic diffusion in tetrahedrons at room temperature.

eISSN:
2083-134X
Sprache:
Englisch
Zeitrahmen der Veröffentlichung:
4 Hefte pro Jahr
Fachgebiete der Zeitschrift:
Materialwissenschaft, andere, Nanomaterialien, Funktionelle und Intelligente Materialien, Charakterisierung und Eigenschaften von Materialien