A Voltammetric Technique Using A Modified Carbon Paste Electrode For The Determination Of Aclonifen
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05. Okt. 2015
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Online veröffentlicht: 05. Okt. 2015
Seitenbereich: 451 - 458
DOI: https://doi.org/10.1515/eces-2015-0026
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© Vít Novotný et al.
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.
A method for the determination of aclonifen at a carbon paste electrode modified with tricresyl phosphate has been developed. The optimum electrochemical regime proved to be differential pulse voltammetry (DPV) in the negative potential range from −200 to −1600 mV. The optimum pH for the determination proved to be pH = 8. The calibration dependence is linear and the limit of detection achieved for the method was 2·10−6 mol/dm3. The method is fast, reliable and it is suitable for the detection of aclonifen in the concentration range from 2·10−6 to 1·10−4 mol/dm3.