<abstract xml:lang="en" xmlns="http://www.w3.org/1999/xhtml"><p>This paper presents the effects of mixing on the course of complex chemical reactions in relation to the manufacturing of pure products at high reaction selectivity, and designing mixing strategies using complex, homogeneous test reaction systems. As an example, the competitive-consecutive and parallel reaction test system including a simultaneous diazo-coupling between 1- and 2-naphtols and diazotized sulphanilic acid is considered. The effect of mixing on the reaction selectivity is interpreted using mechanistic modeling and a new closure scheme. The new closure represents an extension of the conditional PDF closure applied before to simple reaction schemes.</p></abstract>

This paper presents the effects of mixing on the course of complex chemical reactions in relation to the manufacturing of pure products at high reaction selectivity, and designing mixing strategies using complex, homogeneous test reaction systems. As an example, the competitive-consecutive and parallel reaction test system including a simultaneous diazo-coupling between 1- and 2-naphtols and diazotized sulphanilic acid is considered. The effect of mixing on the reaction selectivity is interpreted using mechanistic modeling and a new closure scheme. The new closure represents an extension of the conditional PDF closure applied before to simple reaction schemes.

New closure method for a simultaneous diazo coupling between 1- and 2-Naphthols and diazotized sulphanilic acid

Faculty of Chemical and Process Engineering, Warsaw University of Technology, ul. Waryńskiego 1, 00-645 Warszawa, Poland

Polish Journal of Chemical Technology

This paper presents the effects of mixing on the course of complex chemical reactions in relation to the manufacturing of pure products at high reaction...

New closure method for a simultaneous diazo coupling between 1- and 2-Naphthols and diazotized sulphanilic acid

Published Online: Jun 19, 2009

Page range: 1 - 5

DOI: https://doi.org/10.2478/v10026-009-0016-z

Keywords
closure method, diazo-coupling, micromixing, turbulence

This content is open access.

New closure method for a simultaneous diazo coupling between 1- and 2-Naphthols and diazotized sulphanilic acid

Published Online: Jun 19, 2009

Page range: 1 - 5

DOI: https://doi.org/10.2478/v10026-009-0016-z

Keywordsclosure method, diazo-coupling, micromixing, turbulence

This content is open access.

Keywords
closure method, diazo-coupling, micromixing, turbulence