<abstract xmlns="http://www.w3.org/1999/xhtml">

In this study, a series of Co-based catalysts with alkali metal carbonate promoters were prepared to investigate the interrelation between promotion effect of these carbonates and catalytic performance for aniline hydrogenation to cyclohexylamine in vapour phase. The chemical promoters Li2CO3 and Na2CO3 leading to decrease in catalytic activity of cobalt catalysts for aniline hydrogenation. Catalysts with K2CO3 and Cs2CO3 loadings have practically no catalytic activity for hydrogenation of aniline. Results of TPD of aniline proved that presence of alkali metals carbonates restricts the adsorption of aniline on the surface of cobalt catalysts. Further, it was found that the addition of Na2CO3 greatly enhances the catalytic selectivity towards the cyclohexylamine and inhibits the consecutive reactions of cyclohexylamine leading to formation of by-products such as dicyclohexylamine and <italic>N</italic>-phenylcyclohexylamine.
</abstract>

In this study, a series of Co-based catalysts with alkali metal carbonate promoters were prepared to investigate the interrelation between promotion effect of these carbonates and catalytic performance for aniline hydrogenation to cyclohexylamine in vapour phase. The chemical promoters Li2CO3 and Na2CO3 leading to decrease in catalytic activity of cobalt catalysts for aniline hydrogenation. Catalysts with K2CO3 and Cs2CO3 loadings have practically no catalytic activity for hydrogenation of aniline. Results of TPD of aniline proved that presence of alkali metals carbonates restricts the adsorption of aniline on the surface of cobalt catalysts. Further, it was found that the addition of Na2CO3 greatly enhances the catalytic selectivity towards the cyclohexylamine and inhibits the consecutive reactions of cyclohexylamine leading to formation of by-products such as dicyclohexylamine and N-phenylcyclohexylamine.

Effect of alkali metal promoters on catalytic performance of Co-based catalysts in selective hydrogenation of aniline to cyclohexylamine

Department of Organic Technology, Faculty of Chemical Technology

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution 4.0 International License.

In this study, a series of Co-based catalysts with alkali metal carbonate promoters were prepared to investigate the interrelation between promotion effect of...

Effect of alkali metal promoters on catalytic performance of Co-based catalysts in selective hydrogenation of aniline to cyclohexylamine

Published Online: Mar 29, 2023

Page range: 1 - 7

DOI: https://doi.org/10.2478/pjct-2023-0001

Keywords
Aniline, Cyclohexylamine, Hydrogenation, Cobalt catalyst, Alkali metal carbonate

© 2023 Roman Valeš et al., published by Sciendo

This work is licensed under the Creative Commons Attribution 4.0 International License.

Effect of alkali metal promoters on catalytic performance of Co-based catalysts in selective hydrogenation of aniline to cyclohexylamine

Published Online: Mar 29, 2023

Page range: 1 - 7

DOI: https://doi.org/10.2478/pjct-2023-0001

KeywordsAniline, Cyclohexylamine, Hydrogenation, Cobalt catalyst, Alkali metal carbonate

© 2023 Roman Valeš et al., published by Sciendo

This work is licensed under the Creative Commons Attribution 4.0 International License.

Keywords
Aniline, Cyclohexylamine, Hydrogenation, Cobalt catalyst, Alkali metal carbonate