<abstract xmlns="http://www.w3.org/1999/xhtml">

Hexamethylol melamine resins (HMM) with low crystallization water content and low viscosity were prepared by inhibiting the condensation polymerization of low hexamethylol melamine. The effects of catalyst, pH, formalde-hyde/melamine ratio, reaction temperature and time on the synthesis parameters of HMM were investigated. The results showed that the sample (HMM8) synthesized with Na2CO3-NaHCO3 as catalyst had the crystallization water content lower than 10%, being with a viscosity of about 0.26 Pa·s. The melting temperature of HMM8/polyvinyl alcohol (PVA) curing system was about 164.3 °C. It was found that the higher the amount of formaldehyde, the greater the hydroxyl methyl bounded to each triazine ring. Compared with the traditional melamine formaldehyde resin which had the crystallization water content of about 20–30%, the production of this resin was expected to reduce the energy consumption of industrial reaction, while the resin with 10% crystallization water content was more conducive to the development of alloying HMM/PVA composite membrane.
</abstract>

Hexamethylol melamine resins (HMM) with low crystallization water content and low viscosity were prepared by inhibiting the condensation polymerization of low hexamethylol melamine. The effects of catalyst, pH, formalde-hyde/melamine ratio, reaction temperature and time on the synthesis parameters of HMM were investigated. The results showed that the sample (HMM8) synthesized with Na2CO3-NaHCO3 as catalyst had the crystallization water content lower than 10%, being with a viscosity of about 0.26 Pa·s. The melting temperature of HMM8/polyvinyl alcohol (PVA) curing system was about 164.3 °C. It was found that the higher the amount of formaldehyde, the greater the hydroxyl methyl bounded to each triazine ring. Compared with the traditional melamine formaldehyde resin which had the crystallization water content of about 20–30%, the production of this resin was expected to reduce the energy consumption of industrial reaction, while the resin with 10% crystallization water content was more conducive to the development of alloying HMM/PVA composite membrane.

Preparation of hexamethylol melamine resin with low crystallization water and low viscosity for hexamethylol melamine/polyvinyl alcohol composite membrane

Nano Inorganic Functional Materials Laboratory

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution 4.0 International License.

Hexamethylol melamine resins (HMM) with low crystallization water content and low viscosity were prepared by inhibiting the condensation polymerization of low...

Preparation of hexamethylol melamine resin with low crystallization water and low viscosity for hexamethylol melamine/polyvinyl alcohol composite membrane

Published Online: Apr 13, 2022

Page range: 47 - 56

DOI: https://doi.org/10.2478/pjct-2022-0007

Keywords
low crystallization water content, low energy consumption, low viscosity, hexamethylol melamine/polyvinyl alcohol, composite membrane

© 2022 Xing-Jian Liu et al., published by Sciendo

This work is licensed under the Creative Commons Attribution 4.0 International License.

Preparation of hexamethylol melamine resin with low crystallization water and low viscosity for hexamethylol melamine/polyvinyl alcohol composite membrane

Published Online: Apr 13, 2022

Page range: 47 - 56

DOI: https://doi.org/10.2478/pjct-2022-0007

Keywordslow crystallization water content, low energy consumption, low viscosity, hexamethylol melamine/polyvinyl alcohol, composite membrane

© 2022 Xing-Jian Liu et al., published by Sciendo

This work is licensed under the Creative Commons Attribution 4.0 International License.

Keywords
low crystallization water content, low energy consumption, low viscosity, hexamethylol melamine/polyvinyl alcohol, composite membrane