Open Access

Rapid 90Sr quantification method based on the Bateman equation for routine laboratory work


Cite

Fig. 1

90Sr and 90Y decay scheme [4].
90Sr and 90Y decay scheme [4].

Fig. 2

Flow chart of the 90Sr determination procedure.
Flow chart of the 90Sr determination procedure.

Results from the Procorad 2021 proficiency test

Sample Reference value (Bq·L−1) Bateman equation-based procedure (Bq·L−1)
21SRB 3.11 ± 0.17 3.28 ± 0.56
21SRC 6.06 ± 0.34 6.06 ± 1.03

Statistical evaluation of the 90Sr recovery in immediate and delayed measurements

Fortification level (Bq·kg−1) Immediate Delayed

Mean (%) Median (%) SD (%) n Mean (%) Median (%) SD (%) n
5 85 83 10 12 84 83 4 28
50 82 82 2 12 80 80 3 31
Total 83 82 7 24 82 81 4 59

Validation characteristics of the applied method

Characteristics Result
Linearity 100%
MDA 0.017 Bq·kg−1
Recovery of 90Sr 82%
Relative bias −18%
Repeatability (CV)a 8.5%
Reproducibility (CV)a 9%
Combined standard uncertainty (k = 2)b 17%
eISSN:
1508-5791
Language:
English
Publication timeframe:
4 times per year
Journal Subjects:
Chemistry, Nuclear Chemistry, Physics, Astronomy and Astrophysics, other