<abstract xmlns="http://www.w3.org/1999/xhtml">

In a vacuum environment, when ZnO is prepared using the chemical vapor deposition method and the molecular beam epitaxial growth method, H-gap impurities inevitably remain in the ZnO system, which is often ignored. The study of Zn vacancies under experimental conditions poses a challenge. Second, as an n-type semiconductor, ZnO is characterized by a self-compensation of natural donor defects and poor stability, which severely limit the acquisition of p-type ZnO. Based on the above problems, the conductive properties of S/Se/Te doped and VZn-Hi coexisting ZnO were investigated by first principle to acquire high-stability and high-quality p-ZnO. The study found that Zn35SO35, Zn35SeO35, and Zn35SHiO35 all have good p-type conductivity, which can effectively improve hole mobility and electrical conductivity. Among them, Zn35SO35 has the largest hole concentration at 2.80×1021 cm−3, as well as the best conductivity. The choice of Zn35SO35 provides a reference for obtaining new high-quality p-type ZnO semiconductors.
</abstract>

In a vacuum environment, when ZnO is prepared using the chemical vapor deposition method and the molecular beam epitaxial growth method, H-gap impurities inevitably remain in the ZnO system, which is often ignored. The study of Zn vacancies under experimental conditions poses a challenge. Second, as an n-type semiconductor, ZnO is characterized by a self-compensation of natural donor defects and poor stability, which severely limit the acquisition of p-type ZnO. Based on the above problems, the conductive properties of S/Se/Te doped and VZn-Hi coexisting ZnO were investigated by first principle to acquire high-stability and high-quality p-ZnO. The study found that Zn35SO35, Zn35SeO35, and Zn35SHiO35 all have good p-type conductivity, which can effectively improve hole mobility and electrical conductivity. Among them, Zn35SO35 has the largest hole concentration at 2.80×1021 cm−3, as well as the best conductivity. The choice of Zn35SO35 provides a reference for obtaining new high-quality p-type ZnO semiconductors.

First-principle study on the effect of S/Se/Te doping and VZn-Hi coexistence on ZnO electrical conductivity

College of Materials Science and Engineering

Inner Mongolia Key Laboratory of Thin Film and Coatings

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

First-principle study on the effect of S/Se/Te doping and V-H coexistence on ZnO electrical conductivity

In a vacuum environment, when ZnO is prepared using the chemical vapor deposition method and the molecular beam epitaxial growth method, H-gap impurities...

First-principle study on the effect of S/Se/Te doping and V_Zn-H_i coexistence on ZnO electrical conductivity

Published Online: Mar 30, 2023

Page range: 54 - 63

Received: Jan 17, 2023

Accepted: Feb 26, 2023

DOI: https://doi.org/10.2478/msp-2022-0047

Keywords
ZnO, S/Se/Te doping, H gap, p-type conductivity

© 2022 Yulan Gu et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

First-principle study on the effect of S/Se/Te doping and VZn-Hi coexistence on ZnO electrical conductivity

Published Online: Mar 30, 2023

Page range: 54 - 63

Received: Jan 17, 2023

Accepted: Feb 26, 2023

DOI: https://doi.org/10.2478/msp-2022-0047

KeywordsZnO, S/Se/Te doping, H gap, p-type conductivity

© 2022 Yulan Gu et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

First-principle study on the effect of S/Se/Te doping and V_Zn-H_i coexistence on ZnO electrical conductivity

Keywords
ZnO, S/Se/Te doping, H gap, p-type conductivity