1. bookVolume 38 (2020): Issue 2 (June 2020)
Journal Details
License
Format
Journal
eISSN
2083-134X
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
access type Open Access

Synthesis and characterization of poly(p-phenylenediamine): TiO2 nanocomposites and investigation of conducting properties for optoelectronic application

Published Online: 06 Oct 2020
Volume & Issue: Volume 38 (2020) - Issue 2 (June 2020)
Page range: 296 - 304
Received: 23 Nov 2017
Accepted: 01 Mar 2019
Journal Details
License
Format
Journal
eISSN
2083-134X
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
Abstract

Poly(p-phenylenediamine) is a potential precursor for designing of new materials for optoelectronic application. Synthesis and characterization of poly(p-phenylenediamine) – TiO2 nanocomposites has been demonstrated. Structural change observed due to the formation of nanocomposites was correlated with concomitant change in conducting behavior of the parent polymer. Polymer nanocomposite was synthesized through an in-situ oxidative polymerization technique with simultaneous dispersion of TiO2 nanoparticles. TiO2 nanoparticles were synthesized via sol-gel process. Structural characterization was accomplished by using conventional spectroscopic and imaging techniques. I-V measurement of the nanocomposites revealed that the nearly nonconducting poly(p-phenylenediamine) after structural modification exhibits conductivity of 10−6 S/cm leading to formation of wide band gap semiconducting materials.

Keywords

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