1. bookVolume 27 (2020): Issue 2 (June 2020)
Journal Details
First Published
08 Nov 2011
Publication timeframe
4 times per year
access type Open Access

Study of Methylene Blue Adsorption by Modified Kaolinite by Dimethyl Sulfoxide

Published Online: 17 Jul 2020
Page range: 225 - 239
Journal Details
First Published
08 Nov 2011
Publication timeframe
4 times per year

Tamazert kaolin was modified with dimethyl sulfoxide (DMSO). The starting material and resulting from the intercalation were characterized by X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy (SEM). Intercalation caused considerable changes in our clay by increasing the basal spacing to 11.22 Å, an intercalation rate of 98 %. The adsorption of methylene blue was studied as a function of pH, contact time, temperature, dye concentrations and adsorbents. Kinetic data have been adequately described by the pseudo-second order and intraparticle scattering model. The adsorption isotherm is in good agreement with the Redlich-Peterson model. A change in thermodynamic values (ΔH°, ΔS° and ΔG°) was observed after intercalation. Adsorption became non-spontaneous exothermic and ordered.


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