<abstract xmlns="http://www.w3.org/1999/xhtml">Perovskite is able to sequester simultaneously, in its structure, both actinides and alkaline-earth elements. This study is an attempt to synthesize a complex perovskite Ca0.91-xCe0.09Rb0.04Csx[(Zr0.50Ti0.45)Al0.05]O3 (0.2≤x≤0.4), doped in the same time, with Ce, Cs and Rb. The synthesis is conducted by sintering at 1150°C during 16h. XRX analysis confirms the perovskite formation. SEM observations show a less porous microstructure. FTIR analysis reveals TiO6, Ti-O-Ti, Ti-O and Zr-O vibrations. Raman spectroscopy indicates many orthorhombic perovskite active modes, as: Ti-O6 and Ti-O3 torsions, ZrO7, CaO8 vibrations, the totally symmetric oxygen, and the O-octahedron cage rotation.</abstract>

Perovskite is able to sequester simultaneously, in its structure, both actinides and alkaline-earth elements. This study is an attempt to synthesize a complex perovskite Ca0.91-xCe0.09Rb0.04Csx[(Zr0.50Ti0.45)Al0.05]O3 (0.2≤x≤0.4), doped in the same time, with Ce, Cs and Rb. The synthesis is conducted by sintering at 1150°C during 16h. XRX analysis confirms the perovskite formation. SEM observations show a less porous microstructure. FTIR analysis reveals TiO6, Ti-O-Ti, Ti-O and Zr-O vibrations. Raman spectroscopy indicates many orthorhombic perovskite active modes, as: Ti-O6 and Ti-O3 torsions, ZrO7, CaO8 vibrations, the totally symmetric oxygen, and the O-octahedron cage rotation.

Ftir and Raman Spectroscopic Study of a Complex Perovskite: Ca0.91-XCe0.09Rb0.04Csx[(Zr0.50Ti0.45)Al0.05]O3, X=0.2 to 0.4, Dedicated for Radioactive Waste Confinement

Advances in Materials Science

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Ftir and Raman Spectroscopic Study of a Complex Perovskite: CaCeRbCs[(ZrTi)Al]O, X=0.2 to 0.4, Dedicated for Radioactive Waste Confinement

Perovskite is able to sequester simultaneously, in its structure, both actinides and alkaline-earth elements. This study is an attempt to synthesize a complex...

Ftir and Raman Spectroscopic Study of a Complex Perovskite: Ca_0.91-XCe_0.09Rb_0.04Cs_x[(Zr_0.50Ti_0.45)Al_0.05]O₃, X=0.2 to 0.4, Dedicated for Radioactive Waste Confinement

Published Online: Jun 12, 2020

Page range: 81 - 94

DOI: https://doi.org/10.2478/adms-2020-0012

Keywords
perovskite, radioactive waste, XRD, FTIR, Raman

© 2020 K. Hasnat et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Ftir and Raman Spectroscopic Study of a Complex Perovskite: Ca0.91-XCe0.09Rb0.04Csx[(Zr0.50Ti0.45)Al0.05]O3, X=0.2 to 0.4, Dedicated for Radioactive Waste Confinement

Published Online: Jun 12, 2020

Page range: 81 - 94

DOI: https://doi.org/10.2478/adms-2020-0012

Keywordsperovskite, radioactive waste, XRD, FTIR, Raman

© 2020 K. Hasnat et al., published by Sciendo

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Ftir and Raman Spectroscopic Study of a Complex Perovskite: Ca_0.91-XCe_0.09Rb_0.04Cs_x[(Zr_0.50Ti_0.45)Al_0.05]O₃, X=0.2 to 0.4, Dedicated for Radioactive Waste Confinement

Keywords
perovskite, radioactive waste, XRD, FTIR, Raman