1. bookVolume 12 (2019): Issue 1 (April 2019)
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
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2 times per year
Languages
English
access type Open Access

Bis(3-methylsalicylato)bis(picolinamide)copper(II) complex — preparation, spectral properties and supposed structure

Published Online: 09 Jul 2019
Volume & Issue: Volume 12 (2019) - Issue 1 (April 2019)
Page range: 97 - 102
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
Abstract

Blue methylsalicylatocopper(II) complex with picolinamide Cu(3-Mesal)2(pnia)2 has been prepared and characterized by elemental analysis and spectral methods. Based on the infrared spectra, monodentate coordination of 3-methylsalicylate anion has been assumed and the coordination variability of the anion has been shown. By determination and refinement of the unit cell from powder diffraction data, the existence of a monomeric Cu(II) complex can be anticipated. EPR spectrum of the complex is in good agreement with these results. The g-factors fulfil the relation g|| > g > 2.0023, which is consistent with the dx2 – y2 ground electronic state and indicates coordination sphere of distorted tetragonal symmetry {CuN2O2O2´} for the central copper(II) ions.

Keywords

Bakiler M, Blukbasi O, Yilmaz A (2007) J. Mol. Struct. 826: 6.Search in Google Scholar

Boultif A, Louer D (2004) J. Appl. Crystallogr. 37(5): 724.Search in Google Scholar

Bozkurt N, Dilek N, Caylak Delibas N, Necefoglu H, Hökelek T, Saka G, Tercan B, Cimen E, Necefoglu H (2013) Acta Crystallogr. Sect. E: Struct. Rep. Online 69: m356.Search in Google Scholar

Goodman BA, Raynor JB (1970) Adv. Inorg. Chem. Radiochem. 13: 135.Search in Google Scholar

Groom CR, Bruno IJ, Lightfoot MP, Ward SC (2016) Acta Cryst. B72: 171.Search in Google Scholar

Hathaway BJ, Tomlinson AAG (1970a) Coord. Chem. Rev. 5: 1.Search in Google Scholar

Hathaway BJ, Billing DE (1970b) Coord. Chem. Rev. 5: 43.Search in Google Scholar

Halaška J, Čechová D, Lawson MK, Růzičková Z, Jorík V, Koman M, Valko M, Kozlevčar B, Moncol J (2016) Chem. Papers 70: 101.Search in Google Scholar

Hökelek T, Saka G, Tercan B, Cimen E, Necefoglu H (2010) Acta Crystallogr. Sect. E: Struct. Rep. Online 66: m955.Search in Google Scholar

Kozlevčar B, Leban I, Turel I, Segedin P, Petric M, Pohleven F, White AJP, Williams DJ, Sieler J (1999) Polyhedron 18: 755.Search in Google Scholar

Köse DA, Necefoglu H, Sahin O, Buyukgungor O (2011) J. Chem. Cryst. 41: 297.Search in Google Scholar

Macrae CF, Bruno IJ, Chisholm JA, Edgington PR, McCabe P, Pidcock E, Rodriguez-Monge L, Taylor R, van de Streek J, Wood PA (2008)J. Appl. Cryst. 41: 466.10.1107/S0021889807067908Search in Google Scholar

Moncol J, Maroszova J, Koman M, Melnik M, Valko M, Mazur M, Lis T (2008) J. Coord. Chem. 61: 3740.Search in Google Scholar

Moncol J, Mudra M, Lonnecke P, Hewitt M, Valko M, Morris H, Svorec J, Melnik M, Mazúr M, Koman M (2007) Inorg. Chim. Acta 360: 3213.Search in Google Scholar

Nakamoto K (2009) Infrared and Raman spectra of inorganic and coordination compounds, Part B, John Wiley&Sons, Inc, 118.10.1002/9780470405888Search in Google Scholar

Özbek FE, Sertcelik M, Yuksek M, Necefoglu H, Celik RC, Nayir GY, Hökelek T (2017) J. Mol. Struct. 1150: 112.Search in Google Scholar

Öztürk F, Bulut A, Paşaoglu H, Bulut I, Büyükgüngör O (2012) Spect. Chim. Acta: Part A: 97: 24.Search in Google Scholar

Petříček V, Dušek, M, Palatinus L (2014) Z. Kristallogr. Cryst. 229(5): 345.Search in Google Scholar

Puchoňová M, Matejová S, Jorík V, Šalitroš I, Švorc Ľ, Mazúr M, Moncol J, Valigura D (2018) Polyhedron 151: 152.10.1016/j.poly.2018.05.036Search in Google Scholar

Puchoňová M, Repická Z, Moncol J, Růžičková Z, Mazúr M, Valigura D (2015) J. Mol. Struct. 1092: 1.Search in Google Scholar

Repická Z, Moncol J, Puchoňová M, Jorík V, Mikloš D, Lis T, Padělková Z, Mazúr M, Valigura D (2010) Struct. Chem. 21(5): 1093.Search in Google Scholar

Shiekh RA, Said MA, Malik MA, Hashmi AA (2018) Trop. J. Pharm. Research. 17 (5): 865.Search in Google Scholar

Sieron L (2004) Acta Crystallogr. Sect. E: Struct. Rep. Online 60: m297.Search in Google Scholar

Sieron L (2007) Acta Crystallogr. Sect. E: Struct. Rep. Online 63: m862.Search in Google Scholar

Taylor JR (1997) An introduction to error analysis. Sausalito, Calif: University Science Books.Search in Google Scholar

Thiele H, Etstling J, Such P, Hoefe P (1992) WINEPR, Bruker Analytic Gmb, Germany.Search in Google Scholar

Toby BH (2005) J. Appl. Crystallogr. 38(6): 1040.Search in Google Scholar

Valigura D, Moncol J, Korabik M, Pučeková Z, Lis T, Mrozinski J, Melník M (2006) Eur. J. Inorg. Chem. 3813.Search in Google Scholar

Zvimba JN, Jackson GE (2007) J. Inorg. Biochem. 101: 148.Search in Google Scholar

Weber RT (1995) WINEPR SimFonia, EPR Division, Bruker Instr. Inc., Billerica, USA.Search in Google Scholar

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