1. bookVolume 6 (2013): Issue 1 (April 2013)
Journal Details
License
Format
Journal
eISSN
1339-3065
ISSN
1337-978X
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
access type Open Access

A new pathway of preparation and refined structure of (NH4)2[FeCl5(H2O)]

Published Online: 22 May 2013
Volume & Issue: Volume 6 (2013) - Issue 1 (April 2013)
Page range: 129 - 132
Journal Details
License
Format
Journal
eISSN
1339-3065
ISSN
1337-978X
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
Abstract

The title compound, (NH4)2[FeCl5H2O] has been prepared by reaction between iron(III) chloride and ammonium chloride which was formed by hydrolysis of isonicotinamide or thionicotinamide in ethanol. The characterization was based on elemental analysis and infrared spectra. The crystal structure of the title compound has been refined by single crystal X-ray diffraction method at 293 K. Crystals are orthorhombic, Pnma, with unit cell parameters: a = 13.760(1) A, b = 9.960(1) A, c = 7.060(1) A, Z = 4 and R = 3.5 %. The iron(III) atom in [FeCl5(H2O)]2- ion is approximately octahedrally coordinated by five Cl atoms and one O atom of H2O molecule. This distortion is caused by the extensively hydrogen-bonded lattice. Structural parameters and IR spectra of similar compounds are compared and discussed.

Keywords

Attenborough M, Hall I, Nikolov O, Brown SR, (1997) Hyperfine Interactions 108: 435-442.10.1023/A:1012651921896Search in Google Scholar

Carlin RL, Palacio F (1985) Coord. Chem. Rev. 65: 141-165.Search in Google Scholar

Farrugia LJ (1997) J. Appl. Cryst 30: 565-566.10.1107/S0021889897003117Search in Google Scholar

Farrugia LJ (1999) J. Appl. Cryst 32: 837-838.10.1107/S0021889899006020Search in Google Scholar

Figgis BN, Raston CL, Sharma RP, White AH (1978) Aust. J. Chem. 31: 2717-2720.Search in Google Scholar

James BD, Bakalova M, Liesegang J, Feiff WM, Skelton BW, White AH (2001) Inorg. Chem. 40: 4617-4622.Search in Google Scholar

James BD, Mrozinski J, Klak J, Skelton BW, White AH, (2007) Z. Anorg. Allg. Chem. 663: 2683-2688.Search in Google Scholar

James BD, Mrozinski J, Klak J, Skelton BW, White AH (2007) Z. Anorg. Allg. Chem. 633: 974-978.Search in Google Scholar

Jellinek HHG, Urwin JR (1953) J. Phys. Chem. 57: 900-902.Search in Google Scholar

Macrae CF, Edgington PR, McCabe P, Pidcock E, Shields GP, Taylor R, Towler M, van de Streek J (2006) J. Appl. Cryst 39: 453-457.10.1107/S002188980600731XSearch in Google Scholar

McElearney JN, Merchant S (1978) Inorg. Chem. 17: 1207-1215.Search in Google Scholar

Nakamoto Kazuo (2009). In: Infrared and Raman Spectra of Inorganic and Coordination Compounds; Part A: Theory and Applications in Inorganic Chemistry, Wiley.10.1002/9780470405888Search in Google Scholar

O’Conor ChJ, Deaver BS Jr, Sinn E (1979) J. Chem. Phys. 70: 5161-5167.Search in Google Scholar

Ondrejkovičova I, Galkova S, Mrozinski J, Kłak J, Lis T, Olejnik Z (2008) Inorg. Chim. Acta 361: 2483-2490.Search in Google Scholar

Ondrejkovičova I, Wrzecion M, Nahorska M, Mrozinski J (2009) Polish J. Chem. 83: 1547-1553.Search in Google Scholar

Partiti CSM, Piccini A, Rechenberg HR (1985) Solid State Commun. 56: 687-691.Search in Google Scholar

Piszczek P, Grodzicki A, Engelen B (2003) J. Mol. Struct. 646: 45-54.Search in Google Scholar

Sharma SK, Pandya DK (1974) J. Inorg. Nucl. Chem. 36: 1165-1166.Search in Google Scholar

Sheldrick GM (1990) Acta Cryst. A46: 467-473.Search in Google Scholar

Sheldrick GM (1985) SHELXS-86. In: Sheldrick, GM, Krueger R, Goddard R (Eds) Crystallographic Computing 3, Oxford University Press, 175.Search in Google Scholar

Sheldrick GM (2008) Acta Cryst. A64: 112-122.Search in Google Scholar

Siemens (1990) XEMP. Version 4.2, Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA.Search in Google Scholar

Siemens (1994) Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA.Search in Google Scholar

Smith BC, Anderson MA, Hoadley KA, Keck JL, Cleland WW, Denu JM (2012) Biochemistry 51: 243-256.10.1021/bi2015508325752122229411Search in Google Scholar

Sotofte I, Nielsen K (1981) Acta Chem. Scand. A 35: 821-822.Search in Google Scholar

Subramanian S, Zaworotko MJ (1993) Can. J. Chem. 71: 433-440.Search in Google Scholar

Štefankova S, Ondrejkovičova I, Koman M, Lis T, Mrozinski J, Wrzecion (2008) J. Coord. Chem. 61: 3895-3903.Search in Google Scholar

Recommended articles from Trend MD

Plan your remote conference with Sciendo