<abstract xmlns="http://www.w3.org/1999/xhtml">60P2O5-40Fe2O3 glass was synthesized and 57Fe Mössbauer spectroscopy study was presented. The main goal of the research was to investigate structural changes of local environment of iron ions during gradual crystallization of the glass. It was observed that some changes were evidenced at temperature of heat treatment higher than 400°C, above which content of tetrahedrally coordinated Fe3+ was increased in cost of octahedral sites. This led to formation of areas of nucleation of α-FePO4. Crystallization of α-Fe3(P2O7)2 and Fe2P2O7 was also observed.</abstract>

60P2O5-40Fe2O3 glass was synthesized and 57Fe Mössbauer spectroscopy study was presented. The main goal of the research was to investigate structural changes of local environment of iron ions during gradual crystallization of the glass. It was observed that some changes were evidenced at temperature of heat treatment higher than 400°C, above which content of tetrahedrally coordinated Fe3+ was increased in cost of octahedral sites. This led to formation of areas of nucleation of α-FePO4. Crystallization of α-Fe3(P2O7)2 and Fe2P2O7 was also observed.

Mössbauer spectroscopy study of 60P2O5-40Fe2O3 glass crystallization

Faculty of Materials Science and Ceramics, AGH – University of Science and Technology, 30 Mickiewicza Ave., 30-059 Kraków, Poland, Tel.: +48 12 617 2465

Institute of Electron Technology Krakow Division, Zablocie 39, 30-701 Kraków, Poland

Nukleonika

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mössbauer spectroscopy study of 60PO-40FeO glass crystallization

60P2O5-40Fe2O3 glass was synthesized and 57Fe Mössbauer spectroscopy study was presented. The main goal of the research was to investigate structural changes...

Mössbauer spectroscopy study of 60P₂O₅-40Fe₂O₃ glass crystallization

Published Online: Mar 12, 2015

Page range: 133 - 136

Received: Jun 18, 2014

Accepted: Nov 02, 2014

DOI: https://doi.org/10.1515/nuka-2015-0028

Keywords
crystallization, iron phosphate glass, Mössbauer spectroscopy, nuclear waste, waste glass

© Paweł Stoch, Agata Stoch

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mössbauer spectroscopy study of 60P2O5-40Fe2O3 glass crystallization

Published Online: Mar 12, 2015

Page range: 133 - 136

Received: Jun 18, 2014

Accepted: Nov 02, 2014

DOI: https://doi.org/10.1515/nuka-2015-0028

Keywordscrystallization, iron phosphate glass, Mössbauer spectroscopy, nuclear waste, waste glass

© Paweł Stoch, Agata Stoch

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Mössbauer spectroscopy study of 60P₂O₅-40Fe₂O₃ glass crystallization

Keywords
crystallization, iron phosphate glass, Mössbauer spectroscopy, nuclear waste, waste glass