<abstract xmlns="http://www.w3.org/1999/xhtml"><p>Three dimensional cross-linked polymer microgels with temperature responsive N-isopropyl acrylamide (NIPAM) and pH sensitive methacrylic acid (MAA) were successfully synthesized by free radical emulsion polymerization with different amounts of MAA. Silver and gold nanoparticles with the size of 6.5 nm and 3.5 nm (±0.5 nm), respectively were homogeneously reduced inside these materials by chemical reduction method at pH 2.78 and 8.36 for the preparation of hybrid materials. The samples were characterized by FT-IR, DLS and TEM techniques. The catalytic activity of the hybrid materials was investigated for the reduction of 4-nitrophenol (4-NP) using NaBH4 as reducing agent by UV-Vis spectroscopy. The hybrid polymer network synthesized at pH 8.36 showed enhanced catalytic efficiency compared to the catalysts synthesized at pH 2.78. In this study, it has been stated that the catalyst activity strongly depends on the amount of MAA, pH value during synthesis and the type of entrapped metal nanoparticles. </p></abstract>

Three dimensional cross-linked polymer microgels with temperature responsive N-isopropyl acrylamide (NIPAM) and pH sensitive methacrylic acid (MAA) were successfully synthesized by free radical emulsion polymerization with different amounts of MAA. Silver and gold nanoparticles with the size of 6.5 nm and 3.5 nm (±0.5 nm), respectively were homogeneously reduced inside these materials by chemical reduction method at pH 2.78 and 8.36 for the preparation of hybrid materials. The samples were characterized by FT-IR, DLS and TEM techniques. The catalytic activity of the hybrid materials was investigated for the reduction of 4-nitrophenol (4-NP) using NaBH4 as reducing agent by UV-Vis spectroscopy. The hybrid polymer network synthesized at pH 8.36 showed enhanced catalytic efficiency compared to the catalysts synthesized at pH 2.78. In this study, it has been stated that the catalyst activity strongly depends on the amount of MAA, pH value during synthesis and the type of entrapped metal nanoparticles.

Fabrication of Ag and Au nanoparticles in cross-linked polymer microgels for their comparative catalytic study

Materials Science-Poland

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Three dimensional cross-linked polymer microgels with temperature responsive N-isopropyl acrylamide (NIPAM) and pH sensitive methacrylic acid (MAA) were...

Fabrication of Ag and Au nanoparticles in cross-linked polymer microgels for their comparative catalytic study

Published Online: Oct 31, 2017

Page range: 651 - 659

Received: Apr 03, 2017

Accepted: Aug 25, 2017

DOI: https://doi.org/10.1515/msp-2017-0073

Keywords
cross-linked polymer microgels, free radical polymerization, metal nanoparticles, catalytic activity, comparative study

© 2017

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Fabrication of Ag and Au nanoparticles in cross-linked polymer microgels for their comparative catalytic study

Published Online: Oct 31, 2017

Page range: 651 - 659

Received: Apr 03, 2017

Accepted: Aug 25, 2017

DOI: https://doi.org/10.1515/msp-2017-0073

Keywordscross-linked polymer microgels, free radical polymerization, metal nanoparticles, catalytic activity, comparative study

© 2017

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 License.

Keywords
cross-linked polymer microgels, free radical polymerization, metal nanoparticles, catalytic activity, comparative study