1. bookVolume 35 (2017): Issue 3 (October 2017)
Journal Details
License
Format
Journal
eISSN
2083-134X
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
access type Open Access

Synthesis, growth and characterization of organic crystal triphenylmethane p-nitroaniline: a nonlinear optical crystal

Published Online: 31 Oct 2017
Volume & Issue: Volume 35 (2017) - Issue 3 (October 2017)
Page range: 667 - 672
Received: 26 Apr 2017
Accepted: 17 Aug 2017
Journal Details
License
Format
Journal
eISSN
2083-134X
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
Abstract

A triphenylmethane-4-nitroaniline salt has been synthesized and the crystals have been grown by using slow evaporation solution growth technique. The grown single crystal was investigated by recording the powder XRD, FT-IR spectrum, UV-Vis spectrum, Vickers microhardness test, dielectric measurements and powder SHG. The growth of crystal was confirmed by analyzing the XRD pattern and it was stated that the grown material crystallized in triclinic system. Vibrational peaks of the functional groups existing in the compound were identified. Vickers microhardness studies were carried to measure the mechanical strength. In order to identify the phase transition temperature, the dielectric studies were carried out at different temperatures. Dielectric constant, dielectric loss and impedance of the crystal were monitored with respect to the frequency of electric field.

Keywords

[1] CHEMLA D.S., ZYSS J., Nonlinear optical properties of organic molecules and crystals, Academic Press, New York, 1987.Search in Google Scholar

[2] PRASAD P.N., WILLIAMS D.J., Introduction to nonlinear optical effects in organic molecules and polymers, Wiley, New York, 1991.Search in Google Scholar

[3] HARI SINGH NALWA, SEIZO MIYATA, Nonlinear optics of organic molecules and polymers, CRC Press, Boca Raton, 1997.10.1117/1.601490Search in Google Scholar

[4] MOHAN J., Organic Spectroscopy, principles and applications, Alpha Science International Ltd, Harrow, 2004.Search in Google Scholar

[5] KEMP W., Organic spectroscopy, Palgrave Macmillan New York, 1993.Search in Google Scholar

[6] KALSI P., Spectroscopy of organic compounds, Willey Eastern, New Delhi, 1985.Search in Google Scholar

[7] DANI V.R., Organic spectroscopy, Tata Mc Graw Hill, New Delhi, 1995.Search in Google Scholar

[8] BARZOUKAS M., JOSSE D., FREMAUX P., ZYSS J., NICOUD F., MORLEY J.O., J Opt. Soc. Am. B., 4 (1987), 977.10.1364/JOSAB.4.000977Search in Google Scholar

[9] http://www.chemicalbook.com/ChemicalProductProperty_EN_CB5689132.htm.Search in Google Scholar

[10] MEJEBA M.X., DEVARAJAN P.A., In. J. Eng. Res. Tech., 4 (2015), 952.Search in Google Scholar

[11] PRASAD G.L., KRISHNAKUMAR V., NAGALAKSHMI R., Spectrochim. Acta A, 110 (2013), 377.10.1016/j.saa.2013.03.014Search in Google Scholar

[12] BOOPATHI K., RAMASAMY P., Optik, 126 (2015), 2125.10.1016/j.ijleo.2015.05.080Search in Google Scholar

[13] MARDER S.R., KIPPELEN B., JEN A.K.Y., PEYGHAMBARIAN N., Nature, 388 (1997), 84510.1038/42190Search in Google Scholar

[14] KATZ H.E., SINGER K.D., SOHN J.E., DIRK C.W., KING L.A., GORDEN H.M., J. Am. Chem. Soc., 109 (1987), 6561.10.1021/ja00255a079Search in Google Scholar

[15] BRESLOW R., CHU W., J. Am. Chem. Soc., 92 (1969), 2165.10.1021/ja00710a077Search in Google Scholar

[16] JAGADEESH M.R., SURESH KUMAR H.M., ANANDA KUMAR R., Mater. Sci.-Poland, 33 (2015) 529.10.1515/msp-2015-0063Search in Google Scholar

[17] RENFROW JR. W.B., HAUSER C.R., Org. Synth. Coll., 2 (1943), 607.Search in Google Scholar

[18] NORRIS J.F., Org. Synth. Coll., 1 (1941), 548.Search in Google Scholar

[19] SANGWAL K., Mater. Chem. Phys., 63 (2000), 145.10.1016/S0254-0584(99)00216-3Open DOISearch in Google Scholar

[20] IKEDA H., SAKAI T., KAWASAKI K., Chem. Phys. Lett, 179 (1991), 551.10.1016/0009-2614(91)87101-GSearch in Google Scholar

[21] DMITRIEV V.G., GURZADYAN G.G., NIKOGOSYAN D.N., Nonlinear Optical Crystals, Springer, Berlin 1991.10.1007/978-3-662-13830-4Search in Google Scholar

[22] KURTZ S.K., PERRY T.T., J. Appl. Phys., 39 (1968), 39.10.1063/1.1656857Search in Google Scholar

Recommended articles from Trend MD

Plan your remote conference with Sciendo