1. bookVolume 35 (2017): Issue 2 (July 2017)
Journal Details
License
Format
Journal
eISSN
2083-134X
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
access type Open Access

Studies on structure, growth and characterization of third order nonlinear optical 2-amino-5-chloropyridinium-4-amino benzoate single crystal

Published Online: 26 Jul 2017
Volume & Issue: Volume 35 (2017) - Issue 2 (July 2017)
Page range: 313 - 321
Received: 18 Jun 2016
Accepted: 15 May 2017
Journal Details
License
Format
Journal
eISSN
2083-134X
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
Abstract

Optically transparent single crystals of 2-amino-5-chloropyridinium-4-amino benzoate (2A5CP4AB) were grown at room temperature using solution growth technique. The structure was solved with a support of single crystal XRD, which revealed that the title compound belongs to the monoclinic crystal system having centrosymmetric space group P21/n. The UV-Vis spectrum and photoluminescence properties of the title compound showed the optical transmittance and emission behavior of the compound. The optical band gap was evaluated using the Tauc plot and it was found to be about 3.53 eV. The third order nonlinear optical behavior of the crystal was determined using Z-scan technique. Mechanical properties of the title compound were studied using Vickers microhardness study.

Keywords

[1] PERIYASAMY B.K., JEBAS R.S., THAILAMPILLAI B., Mater. Lett., 61 (2007), 1489.10.1016/j.matlet.2006.07.069Search in Google Scholar

[2] PRASAD P.N., WILLIAMS D.J., Introduction to Nonlinear Optical Effects in molecules and Polymers, Wiley, New York, 1991.Search in Google Scholar

[3] CAROLIN M.L., VASUDEVAN S., Mater. Lett., 62 (2008), 2245.10.1016/j.matlet.2007.11.059Search in Google Scholar

[4] ANANDHA BABU G., SREEDHAR S., VENUGOPAL R., RAMASAMY P., J. Cryst. Growth, 312 (2010), 1957.10.1016/j.jcrysgro.2010.03.017Search in Google Scholar

[5] SANTHAKUMARI S., RAMAMURTHI K., Spectrochim. Acta A, 78 (2011), 653.10.1016/j.saa.2010.11.04321186136Search in Google Scholar

[6] DHANRAJ P.V., RAJESH N.P., VINITHA G., BHAGAVANNARAYANA G., Mater. Res. Bull., 46 (2011), 726.10.1016/j.materresbull.2011.01.013Search in Google Scholar

[7] BRAHADEESWARAN S., ONDUKA S., TAKAGI M., TAKAHASHI Y., ADACHI H., YOSHIMURA M., MORI Y., SASAKI T., J. Cryst. Growth, 292 (2006), 441.10.1016/j.jcrysgro.2006.04.052Search in Google Scholar

[8] BRAHADEESWARAN S., ONDUKA S., TAKAGI M., TAKAHASHI Y., ADACHI H., KAMIMURA T., YOSHIMURA M., MORI Y., YOSHIDA K., SASAKI T., Cryst. Growth Des., 6 (2006), 2643.10.1021/cg0505721Search in Google Scholar

[9] ROBINSON F.A., The vitamin Co-factors of Enzyme Systems, Pergamon, London, 1966.10.1016/B978-1-4831-6823-4.50013-6Search in Google Scholar

[10] PAULING L., HAYWARD R., The Architecture of Molecules, W.H. Freeman, San Francisco, 1964.Search in Google Scholar

[11] GRACIN S., RASMUSON A.C., Cryst. Growth Des., 4 (2004), 1013.10.1021/cg049954hSearch in Google Scholar

[12] ETTER M.C., FRANKENBACH G.A., Chem. Mater., 1 (1989), 10.10.1021/cm00001a005Search in Google Scholar

[13] KASHINO S., SUMIDA Y., HAISA M., Acta Crystallogr. B, 28 (1972), 1374.10.1107/S0567740872004339Search in Google Scholar

[14] KASHINO S., Acta Crystallogr. B, 29 (1973), 1836.10.1107/S0567740873005613Search in Google Scholar

[15] RADEMEYER M., OVERBEEK G.E., LILES D.C., Acta Crystallogr. E, 66 (2010), 1634.10.1107/S1600536810047902Search in Google Scholar

[16] BRAHADEESWARAN S., VENKATARAMAN V., BHAT H.L., J. Cryst. Growth, 205 (1999), 544.10.1016/S0022-0248(99)00302-4Search in Google Scholar

[17] WU J.I., GOPALAKRISHNAN R., TAI C. ID., LAW C.W., Jpn. J. Appl. Phys., 43 (2004), 1507.10.1143/JJAP.43.1507Search in Google Scholar

[18] SHANMUGAM G., BRAHADEESWARAN S., Spectrochim. Acta A, 95 (2012), 177.10.1016/j.saa.2012.04.100Search in Google Scholar

[19] KWON S.J., JAZBINSEK M., KWON O.P., GUNTER P., Cryst. Growth Des., 10 (2010), 1552.10.1021/cg900882hSearch in Google Scholar

[20] MERCURY 1.3., Cambridge Crystallographic Data centre, CCDC Software Limited, Cambridge, UK, 2004.Search in Google Scholar

[21] KANNAN V., SUGUMAR P., BRAHADEESWARAN S., PONNUSWAMY M.N., Acta Crystallogr. E, 8 (2012), 3187.10.1107/S1600536812043085Search in Google Scholar

[22] FASONE S., GRASSO D., GANDOLFO C., J. Mol. Struct., 20 (1974), 449.10.1016/0022-2860(74)85122-7Search in Google Scholar

[23] SHARMA Y.R., Elementary organic spectroscopy, S. Chand, New Delhi, 1996.Search in Google Scholar

[24] SHANMUGAM G., BELSLEY M.S., ISAKOV D., MATOS KOMAS E.D., NEHRU K., BRAHADEESWARAN S., Spectrochim. Acta A, 95 (2012), 177.Search in Google Scholar

[25] TAUC J.C., The optical properties of solids, Academic Press, North-Holland, 1972.Search in Google Scholar

[26] ARAVINDAN A., SRINIVASAN P., Cryst. Res. Technol., 11 (2007), 1097.10.1002/crat.200710954Search in Google Scholar

[27] SABARIGIRISUN T.C., DHANUSKODI S., Cryst. Res.Technol., 44 (2009), 1297. 10.1002/crat.200900351Search in Google Scholar

[28] WOLFERSBERGER D., FRESSENGEAS N., MAUFOY J., KUGEL G., J. Nonlinear. Opt. Phys., 9 (2000), 441.10.1142/S0218863500000376Search in Google Scholar

[29] THIRUPUGALMANI K., KARTHICK S., SHANMUGAM G., KANNAN V., SRIDHAR B., NEHRU K., BRAHADEESWARAN S., Opt. Mater., 49 (2015), 158.10.1016/j.optmat.2015.09.014Search in Google Scholar

[30] ARUN K.J., JEYALAKSHMI S., Optoelectron. Adv. Mat., 2 (2008), 701.Search in Google Scholar

[31] BOYD R.W., Nonlinear Optics, Elsevier, USA, 2008.Search in Google Scholar

[32] CHEUNG Y.M., GAYEN S.K., J. Opt. Soc. Am. B, 11 (1994) 636.Search in Google Scholar

[33] RODRIGUEZ L., AHN H.Y., BELFIELD D.K., Opt. Express, 17 (2009), 19617.10.1364/OE.17.01961719997182Search in Google Scholar

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