1. bookVolume 10 (2017): Issue 2 (December 2017)
Journal Details
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Journal
eISSN
1339-3065
First Published
10 Dec 2012
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2 times per year
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English
access type Open Access

Hydrogen bonded homodimetallic compounds of the formula [M(H2O)5M(dipic)2]·2H2O, M = CoII or NiII and dipic = dipicolinate anion

Published Online: 29 Dec 2017
Volume & Issue: Volume 10 (2017) - Issue 2 (December 2017)
Page range: 132 - 138
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
Abstract

Two homodimetallic dipicolinate compounds of the formulae [Co(H2O)5Co(dipic)2]·2H2O (1) and [Ni(H2O)5Ni(dipic)2]·2H2O (2) have been synthesized and their crystal structures have been determined by single-crystal X-ray diffraction analysis. The prepared isostructural compounds consist of cationic {MO5O’}2+ and anionic {MN2O4}2- moieties, where CoII/CoII or NiII/NiII metal centers are connected together by bridging μ-carboxylate oxygen atoms from dipicolinate anions. H-bond interactions involving aqua ligands, dipicolinate oxygens and lattice solvent molecules stabilize the dimeric units by linking them into 3-D polymeric networks.

Keywords

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