1. bookVolume 10 (2017): Issue 1 (April 2017)
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
access type Open Access

Crystal and electronic structure, N–H⋯N and C–H⋯O interactions in novel spiro-[chroman-chromene]-carboxylate

Published Online: 23 Jun 2017
Volume & Issue: Volume 10 (2017) - Issue 1 (April 2017)
Page range: 74 - 78
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
Abstract

We report here the structure of new spiro-derivative, namely methyl (2R,4R)-4-(5-methylthiazol- 2-ylamino)spiro[chroman-2,2’-chromene]-3’-carboxylate, C23H20N2O4S, which crystallizes as racemate in the space group P-1. In this compound, the chromanone moiety consists of a benzene ring fused with a sixmembered heterocyclic ring which adopts a distorted half-chair conformation. The molecules are linked by a combination of N–H⋯N hydrogen bonds and weak C–H⋯O, C-H⋯S, C-H⋯π, inter- and intramolecular interactions resulting in a two-dimensional network in the crystal structure.

Keywords

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