<abstract xmlns="http://www.w3.org/1999/xhtml">Crystal structures of the title compounds, [Mn(N3)2(phen)2] (<bold>1</bold>), [Co(N3)2(phen)2] (<bold>2</bold>) and [Cu(N3)2(phen)2] · 1.5 H2O (<bold>3</bold>), have been determined at 100 K. Central atoms of the above-mentioned compounds are coordinated by four pyridine nitrogen donor atoms from two 1,10-phenanthroline molecules and two nitrogen donor atoms of terminally coordinated azide anions, which resulted in a distorted {MN6} octahedral geometry. The π-π stacking interactions, as well as weak C—H∙∙∙N hydrogen bonds, were observed in all three compounds. Moreover, complex 3 revealed also supramolecular chains of the complex and water molecules linked together through O—H∙∙∙N hydrogen bonds.</abstract>

Crystal structures of the title compounds, [Mn(N3)2(phen)2] (1), [Co(N3)2(phen)2] (2) and [Cu(N3)2(phen)2] · 1.5 H2O (3), have been determined at 100 K. Central atoms of the above-mentioned compounds are coordinated by four pyridine nitrogen donor atoms from two 1,10-phenanthroline molecules and two nitrogen donor atoms of terminally coordinated azide anions, which resulted in a distorted {MN6} octahedral geometry. The π-π stacking interactions, as well as weak C—H∙∙∙N hydrogen bonds, were observed in all three compounds. Moreover, complex 3 revealed also supramolecular chains of the complex and water molecules linked together through O—H∙∙∙N hydrogen bonds.

Crystal structures of [M(N3)2(phen)2] compounds, M = Mn, Co or Cu and phen = 1,10-phenanthroline

Faculty of Chemical and Food Technology, Slovak University of Technology, Radlinsky 9, SK-812 37, Bratislava,

Acta Chimica Slovaca

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Crystal structures of [M(N)(phen)] compounds, M = Mn, Co or Cu and phen = 1,10-phenanthroline

Crystal structures of the title compounds, [Mn(N3)2(phen)2] (1), [Co(N3)2(phen)2] (2) and [Cu(N3)2(phen)2] · 1.5 H2O (3), have been determined at 100 K....

Crystal structures of [M(N₃)₂(phen)₂] compounds, M = Mn, Co or Cu and phen = 1,10-phenanthroline

Published Online: Dec 08, 2016

Page range: 152 - 157

DOI: https://doi.org/10.1515/acs-2016-0026

Keywords
azide anions, crystal structures, hydrogen bonds, 1,10-phenanthroline, π-π stacking interactions

© 2016 Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Crystal structures of [M(N3)2(phen)2] compounds, M = Mn, Co or Cu and phen = 1,10-phenanthroline

Published Online: Dec 08, 2016

Page range: 152 - 157

DOI: https://doi.org/10.1515/acs-2016-0026

Keywordsazide anions, crystal structures, hydrogen bonds, 1,10-phenanthroline, π-π stacking interactions

© 2016 Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Crystal structures of [M(N₃)₂(phen)₂] compounds, M = Mn, Co or Cu and phen = 1,10-phenanthroline

Keywords
azide anions, crystal structures, hydrogen bonds, 1,10-phenanthroline, π-π stacking interactions