1. bookVolume 8 (2015): Issue 1 (April 2015)
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
Open Access

Synthesis, structure, thermal decomposition and spectral properties of neutral [Fe(bpta)2(etOH)2(NCS)2]

Published Online: 15 Jun 2015
Volume & Issue: Volume 8 (2015) - Issue 1 (April 2015)
Page range: 78 - 85
Journal Details
License
Format
Journal
eISSN
1339-3065
First Published
10 Dec 2012
Publication timeframe
2 times per year
Languages
English
Abstract

The new iron(II) complex [Fe(bpta)2(EtOH)2(NCS)2] (bpta = 3,3’-(1,2,4-thiadiazole-3,5-diyl) dipyridine; EtOH = ethanol) has been prepared by refluxing Fe(NCS)3 or Fe(NCS)2 with thionicotinamide in an ethanol solution and characterized by elemental analysis, infrared spectroscopy, thermal decomposition and X-ray structural analysis. The characterized compound is a mixture of three regioisomers resulting from differential coordination by the 3- and 5-position 2-pyridyl groups. The bpta ligand was generated in situ by the oxidation dimerization of thionicotinamide. X-ray single-crystal diffraction revealed that the crystal structure is centrosymmetric and the complex crystallizes in the triclinic space group P-1. The iron(II) atom lies in the centre of symmetry and it is octahedrally coordinated by two nitrogen atoms from two thiocyanate anions and two oxygen atoms from ethanol molecules in the equatorial plane and two nitrogen atoms of pyridine rings from two bpta ligands in the axial positions. This complex represents the second example of metal complex with bpta.

Keywords

Allen FH (2002) Acta Cryst B58: 380–388.10.1107/S010876810200389012037359Search in Google Scholar

Aragoni C, Garau A, Isaia F, Lippolis V, Montis R, Pintus A (2012) CrystEngComm 14: 5809–5823.10.1039/c2ce25212kSearch in Google Scholar

Bentiss F, Lebrini M, Vezin H, Lagrenée M (2004) Mat Chem Phys 87: 18–23.10.1016/j.matchemphys.2004.05.040Search in Google Scholar

Bhuvaa H, Sahua D, Shaha B, Modia DC, Patel MB (2011) Pharmacologyonline 1: 528–543.Search in Google Scholar

Boeini HZ (2009) J Iran Chem Soc 6: 547–551.10.1007/BF03246534Search in Google Scholar

Burla MC, Caliandro R, Camalli M, Carrozzini B, Cascarano GL, Giacovazzo C, Mallamo M, Mazzone A, Polidori G, Spagna R (2012) J Appl Crystallogr 45: 357–361.10.1107/S0021889812001124Search in Google Scholar

Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H (2009) J Appl Crystallogr 42: 339–341.10.1107/S0021889808042726Search in Google Scholar

Duisenberg AJM, Kroon-Batenburg LMJ, Schreurs AMM (2003) J Appl Crystallogr 36: 220–229.10.1107/S0021889802022628Search in Google Scholar

Fargašová A, Ondrejkovičová I, Kramarová Z, Fáberová Z (2010) Bioresource Technology 101: 6410–6415.10.1016/j.biortech.2010.03.03620381344Search in Google Scholar

Farrugia LJ (2012) J Appl Crystallogr 45: 849–854.10.1107/S0021889812029111Search in Google Scholar

Klingele J, Kaase D, Hilgert J, Steinfeld G, Klingele MH, Lach (2010) J Chem Soc Dalton Trans 39(19): 495–507.Search in Google Scholar

Klingele J, Kaase D, Klingele MH, Lach J (2012) J. Chem Soc Dalton Trans 41: 1397–1406.10.1039/C1DT11396HSearch in Google Scholar

Leung-Toung R, Wodzinska J, Li W, Lowrie J, Kukreja R, Desilets D, Karimian K, Tam TF (2003) Bioorg Med Chem 11: 5529–5537.10.1016/j.bmc.2003.09.040Search in Google Scholar

Liu JQ, Wang YY, Batten SR, Sakiyama H, Ma DY (2012) Inorg Chem Commun 19: 27–30.10.1016/j.inoche.2012.01.022Search in Google Scholar

Macrae CF, Edgington PR, McCabe P, Pidcock E, Shields GP, Taylor R, Towler M, Streek J (2006) J Appl Crystallogr 39: 453–457.10.1107/S002188980600731XSearch in Google Scholar

Nakamoto K (2009) Infrared and Raman Spectra of inorganic and coordination compounds Part A: Theory and applications in inorganic chemistry, John Wiley & Sons, Inc., Hoboken, New Jersey.Search in Google Scholar

Niu CY, Wu BL, Zheng XF, Zhang HY, Hou HW, Niu YY, Li ZJ (2008) Cryst Growth Des 8: 1566–1574.10.1021/cg700839pSearch in Google Scholar

Ondrejkovičová I, Galková S, Mroziński J, Kłak J, Lis T, Olejnik Z (2008) Inorg. Chim. Acta 361: 2483–2490.Search in Google Scholar

Ondrejkovičová I, Wrzecion M, Nahorska M, Mroziński J (2009) Polish J Chem 83: 1547–1553.Search in Google Scholar

Patil PC, Bhalerao DS, Dangate PS, Akamanchi KG (2009) Tetrahedron Letters 50: 5820–5822.10.1016/j.tetlet.2009.07.155Search in Google Scholar

Ptaszyński B, Skiba E, Krystek J (1998) Thermochimica Acta 319(1-2): 75–85.10.1016/S0040-6031(98)00391-8Search in Google Scholar

Richardson C, Steel PJ, D’Alessandro DM, Junk PC, Keene FR (2002) J Chem Soc Dalton Trans 13: 2775–2785.Search in Google Scholar

Roubeau O, Gamez P, Teat SJ (2013) Eur J Inorg Chem 5-6: 934–942.10.1002/ejic.201201126Search in Google Scholar

Semwal A, Chaudhary B, Singh R, Bagchi A (2013) Int J Pharm Tech Res 3: 1–13.Search in Google Scholar

Sheldrick GM (2003) SADABS, Bruker AXS Inc., Madison, Wisconsin, USA.Search in Google Scholar

Sheldrick GM (2015) Acta Cryst C71: 3–8.10.1107/S2053229614024218429432325567568Search in Google Scholar

Siddiqui N, Ahuja P, Ahsan W, Pandeya SN, Alam MS (2009) J Chem Pharm Res 1: 19–30.Search in Google Scholar

Štefániková S, Ondrejkovičová I, Koman M, Lis T, Mroziński J, Wrzecion M (2008) J Coord Chem 61: 3895–3903.10.1080/00958970802178489Search in Google Scholar

Takikawa Y, Shimada K, Sato K, Sato, S. Takiyawa (1985) Bull Chem Soc Jpn 58: 995–999.10.1246/bcsj.58.995Search in Google Scholar

Uhrecký R, Ondrejkovičová I, Lacková D, Fáberová Z, Mroziński J, Kalińska B, Padělková Z, Koman M (2014) Inorg Chim Acta 414: 33–38.10.1016/j.ica.2014.01.032Search in Google Scholar

Vei RJ, Li B, Huang RB, Zheng LS, Zheng Z (2011) Inorg Chem 50: 1170–1172.10.1021/ic102231j21138318Search in Google Scholar

Zhao XJ, Guo JH, Du M (2005) Acta Cryst E61: m913–m915.10.1107/S1600536805011268Search in Google Scholar

Recommended articles from Trend MD

Plan your remote conference with Sciendo