Comparing monolithic and fused core HPLC columns for fast chromatographic analysis of fat-soluble vitamins

1. B. Kučerová, L. Krčmová, L. Solichova, J. Plíšek and P. Solich, Comparison of a new high-resolution monolithic column with core-shell and fully porous columns for the analysis of retinol and α-tocopherol in human serum and breast milk by ultra-high-performance liquid chromatography, J. Sep. Sci. 36 (2013) 2223-2230; DOI: 10.1002/jssc.201300242.10.1002/jssc.20130024223677738Search in Google Scholar

2. S. Pous-Torres, J. R. Torres-Lapasió and M. C. García-Álvarez-Coque, Comparison of the performance of Chromolith Performance RP-18e, 1.8μm Zorbax Eclipse XDB-C18 and XTerra MS C18, based on modeling approaches, Anal. Bioanal. Chem. 405 (2013) 2219-2231; DOI: 10.1007/s00216-012-6448-y.10.1007/s00216-012-6448-y23099527Search in Google Scholar

3. T. Reddy, G. Balammal and A. Kumar, Ultra performance liquid chromatography: an introduction and review, Int. J. Pharm. Res. Anal. 2 (2012) 24-31.Search in Google Scholar

4. J. M. Cunliffe and T. D. Maloney, Fused-core particle technology as an alternative to sub-2-mm particles to achieve high separation efficiency with low backpressure, J. Sep. Sci. 30 (2007) 3104-3109; DOI: 10.1002/jssc.200700260.10.1002/jssc.20070026018004717Search in Google Scholar

5. J. Kirkland, T. Langlois and J. DeStefano, Fused core particles for HPLC columns, Am. Lab. 39 (2007) 18-21.Search in Google Scholar

6. J. J. Salisbury, Fused-core particles: A practical alternative to sub-2 micron particles, J. Chromatogr. Sci. 46 (2008) 883-886; DOI: 10.1093/chromsci/46.10.883.10.1093/chromsci/46.10.88319007495Search in Google Scholar

7. S. Altmaier and K. Cabrera, Structure and performance of silica-based monolithic HPLC columns, J. Sep. Sci. 31 (2008) 2551-2559; DOI: 10.1002/jssc.200800213.10.1002/jssc.20080021318618471Search in Google Scholar

8. S. El Deeb, B. N. Ma and R. Gust, Determination of NiII(3-OMe-salophene) in MCF7 and HT29 cancer cell lines using HR-CS-AAS and in serum albumin using LC with monolithic silica, Microchem. J. 101 (2012) 24-29; DOI: 10.1016/j.microc.2011.09.013.10.1016/j.microc.2011.09.013Search in Google Scholar

9. M. Taha, A. Abed and S. El Deep, Quality Control of Drugs, in Monolithic Silicas in Separation Science Concepts, Syntheses, Characterization, Modelling and Applications (Eds. K. Unger, N. Tanaka and E. Machtejevas), 1st ed., Wiley-VCH, Weinheim-Germany 2011, pp. 189-201.10.1002/9783527633241.ch10Search in Google Scholar

10. S. El Deeb, U. Schepers and H. Wätzig, Evaluation of monolithic C18 HPLC columns for the fast analysis of pilocarpine hydrochloride in the presence of its degradation products, Pharmazie 61 (2006) 751-756.Search in Google Scholar

11. S. El Deeb and H. Wätzig, Performance comparison between monolithic C18 and conventional C18 particle-packed columns in the liquid chromatographic determination of propranolol HCl, Turk. J. Chem, 30 (2006) 543-552.Search in Google Scholar

12. S. El Deeb, L. Preu and H. Wätzig, A strategy to develop fast RP-HPLC methods using monolithic silica columns, J. Sep. Sci. 30 (2007) 1993-2001; DOI: 10.1002/jssc.200700092.10.1002/jssc.20070009217625793Search in Google Scholar

13. S. El Deeb, L. Preu and H. Wätzig, Evaluation of monolithic HPLC columns for various pharmaceutical separations: method transfer from conventional phases and batch to batch repeatability, J. Pharm. Biomed. Anal. 44 (2007) 85-95; DOI: 10.1016/j.jpba.2007.01.045.10.1016/j.jpba.2007.01.04517346916Search in Google Scholar

14. S. El Deeb, U. Schepers and H. Wätzig, Fast HPLC method for the determination of glimepiride, glibenclamide, and related substances using monolithic column and flow program, J. Sep. Sci. 29 (2006) 1571-1577; DOI: 10.1002/jssc.200600056.10.1002/jssc.20060005616922272Search in Google Scholar

15. W. S. Khayoon, B. Saad, B. Salleh, N. A. Ismail, N. A. Abdul Manaf and A. A. Latiff, A reversed phase high performance liquid chromatography method for the determination of fumonisins B1 and B2 in food and feed using monolithic column and positive confirmation by liquid chromatography/tandem mass spectrometry, Anal. Chim. Acta 679 (2010) 91-97; DOI:10.1016/j.aca.2010.09.008.10.1016/j.aca.2010.09.00820951862Search in Google Scholar

16. H. Y. Aboul-Enein, I. Ali and H. Hoenen, Rapid determination of haloperidol and its metabolites in human plasma by HPLC using monolithic silica column and solid-phase extraction, Biomed. Chromatogr. 20 (2006) 760-764; DOI: 10.1002/bmc.593.10.1002/bmc.59316261544Search in Google Scholar

17. M. Hefnawy, M. Al-Omar and S. Julkhuf, Rapid and sensitive simultaneous determination of ezetimibe and simvastatin from their combination drug products by monolithic silica high-performance liquid chromatographic column, J. Pharm. Biomed. Anal. 50 (2009) 527-534; DOI: 1.1016/j.jpba.2009.05.002.10.1016/j.jpba.2009.05.00219487095Search in Google Scholar

18. L. Kaminski, S. El Deeb and H. Wätzig, Repeatability of monolithic HPLC columns while using a flow program, J. Sep. Sci. 31 (2008) 1745-1749; DOI: 10.1002/jssc.200700681.10.1002/jssc.20070068118446815Search in Google Scholar

19. S. Pous-Torres, J. R. Torres-Lapasió, M. J. Ruiz-Angel and M.C. García-Alvarez-Coque, Interpretive optimisation of organic solvent content and flow-rate in the separation of beta-blockers with a Chromolith RP-18e column, J. Sep. Sci. 32 (2009) 2793-2803; DOI: 10.1002/jssc.200900137.10.1002/jssc.20090013719603390Search in Google Scholar

20. K. Cabrera, D. Lubda, H. M. Eggenweiler, H. Minakuchi and K. Nakanishi, A new monolithictype HPLC column for fast separations, J. High Res. Chromatogr. 23 (2000) 93-99; DOI: 10.1002/(SICI)1521-4168(20000101)23.Search in Google Scholar

21. D. Cabooter, K. Broeckhoven, R. Sterken, A. Vanmessen, I. Vandendael, K. Nakanishi, S. Deridder and G. Desmet, Detailed characterization of the kinetic performance of first and second generation silica monolithic columns for reversed-phase chromatography separations, J. Chromatogr. A. 1325 (2014) 72-82; DOI: 10.1016/j.chroma.2013.11.047.10.1016/j.chroma.2013.11.04724342534Search in Google Scholar

22. H. Sklenářová, P. Chocholouš, P. Koblová, L. Zahálka, D. Šatínský, L. Matysová and P. Solich, High-resolution monolithic columns-a new tool for effective and quick separation, Anal. Bioanal. Chem. 405 (2013) 2255-2263; DOI: 10.1007/s00216-012-6561-y.10.1007/s00216-012-6561-y23208284Search in Google Scholar

23. S. El Deeb, B. N. Ma and R. Gust, Development and validation of a LC method for the separation and determination of the anticancer-active Fe(III) (4-methoxy-salophene) using the new secondgeneration monolith, J. Sep. Sci. 35 (2012) 3434-3438; DOI: 10.1002/jssc.201200734.10.1002/jssc.20120073423225710Search in Google Scholar

24. R. Dabre, N. Azad, A. Schwämmle, M. Lämmerhofer and W. Lindner, Simultaneous separation and analysis of water- and fat-soluble vitamins on multi-modal reversed-phase weak anion exchange material by HPLC-UV, J. Sep. Sci. 34 (2011) 761-772; DOI: 10.1002/jssc.201000793.10.1002/jssc.20100079321384549Search in Google Scholar

25. S. S. Deshpande, Dietary Constituents, in Handbook of Food Toxicology, CRC Press, Boca Raton 2002, pp.184-193.Search in Google Scholar

26. L. Snyder, J. Kirkland and J. Glajch, Completing the Method: Validation and Transfer, in Practical HPLC Method Development, 2nd ed., Wiley, New York 1997, pp. 710-711.10.1002/9781118592014Search in Google Scholar

27. F. Klink, Improving Electrospray LODs by Decreasing Column Diameter, MS solution#2, Separation Science, 2 (2013).Search in Google Scholar

28. K. Croes, A. Steffens, D. Marchand and L. Snyder, Relevance of π-π and dipole-dipole interactions for retention on cyano and phenyl columns in reversed-phase liquid chromatography, J. Chromatogr. A 1098 (2005) 123-130; DOI: 10.1016/j.chroma.2005.08.090.10.1016/j.chroma.2005.08.09016314168Search in Google Scholar

29. Center for Drug Evaluation and Research (CDER), Reviewer Guidance: Validation of Chromatographic Methods, FDA, Washington (1994.Search in Google Scholar

30. B. Buszewski, and S. Noga, Hydrophilic interaction liquid chromatography (HILIC) - a powerful separation technique, Anal. Bioanal. Chem. 402 (2012) 231-247; DOI: 10.1007/s00216-011-5308-5.10.1007/s00216-011-5308-5324956121879300Search in Google Scholar

31. V. Malik, S. Jain, and P. Malik, HPLC: An analytical technique for pharmaceutical validation of omeprazole, J. Eng. Comp.Appl. Sci. 2 (2013) 1-10.Search in Google Scholar

32. United States Pharmacopeia, USP 30 - NF25, Weight variation of dietary supplement, Rockville (MD) 2007, p. 731.Search in Google Scholar