<abstract xmlns="http://www.w3.org/1999/xhtml">A fast, simple, and economical method for extraction, preconcentration and determination of cobalt, nickel and copper as their 1-(2-pyridilazo) 2-naphthol (PAN) complexes based on ultrasound-assisted emulsification–microextraction (USAEME) and multivariate calibration of spectrophotometric data is presented. Various parameters affecting the extraction efficiency were optimized both with univariate and Box–Behnken design. The resolution of ternary mixtures of these metallic ions was accomplished by using partial least-squares regression (PLS), orthogonal signal correction-partial least-squares regression (OSC-PLS), and orthogonal signal correction-genetic algorithmspartial least-squares regression (OSC-GA-PLS). Under the optimum conditions, the calibration graphs were linear in the range of 2.0–150.0, 2.0–120.0 and 2.0–150.0 ng mL−1 for Co2+, Ni2+, and Cu2+, respectively, with a limit of detection of 0.14 (Co2+), 0.13 (Ni2+) and 0.14 ng mL−1 (Cu2+) and the relative standard deviation was &lt;2.5%. The method was successfully applied to the simultaneous determination of these cations in different samples.</abstract>

A fast, simple, and economical method for extraction, preconcentration and determination of cobalt, nickel and copper as their 1-(2-pyridilazo) 2-naphthol (PAN) complexes based on ultrasound-assisted emulsification–microextraction (USAEME) and multivariate calibration of spectrophotometric data is presented. Various parameters affecting the extraction efficiency were optimized both with univariate and Box–Behnken design. The resolution of ternary mixtures of these metallic ions was accomplished by using partial least-squares regression (PLS), orthogonal signal correction-partial least-squares regression (OSC-PLS), and orthogonal signal correction-genetic algorithmspartial least-squares regression (OSC-GA-PLS). Under the optimum conditions, the calibration graphs were linear in the range of 2.0–150.0, 2.0–120.0 and 2.0–150.0 ng mL−1 for Co2+, Ni2+, and Cu2+, respectively, with a limit of detection of 0.14 (Co2+), 0.13 (Ni2+) and 0.14 ng mL−1 (Cu2+) and the relative standard deviation was <2.5%. The method was successfully applied to the simultaneous determination of these cations in different samples.

Ultrasound-assisted emulsification–microextraction and spectrophotometric determination of cobalt, nickel and copper after optimization based on Box-Behnken design and chemometrics methods

Department of Chemistry, College of Science, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch

Department of Chemistry, Faculty of Science, Arak Branch

Polish Journal of Chemical Technology

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

A fast, simple, and economical method for extraction, preconcentration and determination of cobalt, nickel and copper as their 1-(2-pyridilazo) 2-naphthol...

Ultrasound-assisted emulsification–microextraction and spectrophotometric determination of cobalt, nickel and copper after optimization based on Box-Behnken design and chemometrics methods

Published Online: Apr 16, 2018

Page range: 21 - 28

DOI: https://doi.org/10.2478/pjct-2018-0004

Keywords
ultrasound-assisted emulsification–microextraction, chemometrics, cobalt, nickel, copper

© 2018 Zohreh Doroudi et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Ultrasound-assisted emulsification–microextraction and spectrophotometric determination of cobalt, nickel and copper after optimization based on Box-Behnken design and chemometrics methods

Published Online: Apr 16, 2018

Page range: 21 - 28

DOI: https://doi.org/10.2478/pjct-2018-0004

Keywordsultrasound-assisted emulsification–microextraction, chemometrics, cobalt, nickel, copper

© 2018 Zohreh Doroudi et al., published by De Gruyter Open

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Keywords
ultrasound-assisted emulsification–microextraction, chemometrics, cobalt, nickel, copper