1. bookVolume 31 (2013): Issue 2 (April 2013)
Journal Details
License
Format
Journal
eISSN
2083-134X
ISSN
2083-1331
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
access type Open Access

Synthesis and crystal structure of chlorate-enclathrated in aluminogermanate sodalite Na8[AlGeO4]6(ClO3)2

Published Online: 20 Apr 2013
Volume & Issue: Volume 31 (2013) - Issue 2 (April 2013)
Page range: 246 - 252
Journal Details
License
Format
Journal
eISSN
2083-134X
ISSN
2083-1331
First Published
16 Apr 2011
Publication timeframe
4 times per year
Languages
English
Abstract

Encapsulation of chlorate in sodalite with aluminogermanate host framework has been obtained by one pot hydrothermal synthesis at 393 K. The crystal structure of Na8[AlGeO4]6(ClO3)2; sodalite was refined from X-ray powder data in the space group P$\bar 4$3n: a = 9.169 Å, where Al-O-Ge angle is 137.6°. The 27Al MAS NMR study confirmed alternate Ge and Al ordering of the sodalite framework, while 23Na gave insight into the structure and dynamics of the cage fillings. Infrared spectrum confirmed the encapsulation of chlorate as well as the framework formation of aluminogermanate sodalite. SEM study showed the retention of cubical morphology of the aluminogermanate sodalite. Thermogravimetric analysis provided information on the extent of chlorate entrapment, stability within the sodalite cages and decomposition properties.

Keywords

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